03505

1,2-Dibromoethane

purum, ≥98.0% (GC)

• Synonyme(s) : EDB, Ethylene dibromide
• Formule linéaire : BrCH₂CH₂Br
• Numéro CAS: 106-93-4
• Poids moléculaire : 187.86
• Numéro Beilstein : 605266
• Numéro CE : 203-444-5
• Numéro MDL: MFCD00000233
• Code UNSPSC : 12352100
• ID de substance PubChem : 329747727
• Nomenclature NACRES : NA.22

Propriétés

• Densité de vapeur: ~6.5 (vs air)
• Niveau de qualité: 200
• Pression de vapeur: 11.7 mmHg ( 25 °C)
• Qualité: purum
• Pureté: ≥98.0% (GC)
• Forme: liquid
• Indice de réfraction: n20/D 1.539 (lit.); n20/D 1.539
• Point d'ébullition: 131-132 °C (lit.)
• Pf: 8-11 °C (lit.)
• Densité: 2.18 g/mL at 25 °C (lit.)
• Chaîne SMILES: BrCCBr
• InChI: 1S/C2H4Br2/c3-1-2-4/h1-2H2
• Clé InChI: PAAZPARNPHGIKF-UHFFFAOYSA-N

Description

Description générale

1,2-Dibromoethane (EDB) is a water-soluble dihaloalkane that was widely used as a soil and grain fumigant. This led to the contamination of soil, surface, and groundwater with residual EDB. As it is a potent carcinogen and mutagen, many studies have been conducted to identify chemical reactions for its degradation in the environment.

Application

1,2-Dibromoethane can be used:

• To generate vinyl bromide in situ, which can undergo a palladium-catalyzed cross-coupling reaction with aryl boronic acids to form functionalized styrene derivatives.
• As a brominating agent of tertiary carbanions in sterically hindered molecules.
• As a building block to synthesize 2-arylsulfonyl hydrazones, (±)-horsfiline and 7-oxo-2, 3-dihydro-7H-pyrido [1,2,3-de] [1,4] benzoxazine-6-carboxylic acids.

Informations sur la sécurité

• Pictogrammes: GHS06,GHS08,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H301 + H311 + H331,H315,H319,H335,H350,H411
• Conseils de prudence: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Classification des risques: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter