1.00573

ortho-Phosphoric acid

85%, for analysis EMSURE^® ACS,ISO,Reag. Ph Eur

• Synonyme(s) : Acide phosphorique, Acide orthophosphorique
• Formule linéaire : H₃PO₄
• Numéro CAS: 7664-38-2
• Poids moléculaire : 98.00
• NACRES: NA.21
• UNSPSC Code: 12352301
• MDL number: MFCD00011340
• Beilstein/REAXYS Number: 1921286
• eCl@ss: 38070202

Propriétés

• Nom du produit: Acide orthophosphorique (85 %), for analysis EMSURE^® ACS,ISO,Reag. Ph Eur
• grade: ACS reagent
• Quality Segment: 300
• agency: reag. ISO, reag. Ph. Eur.
• vapor density: 3.4 (vs air)
• vapor pressure: 2.2 mmHg ( 20 °C), 5 mmHg ( 25 °C)
• product line: EMSURE^®
• form: liquid
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 85% phosphoric acid
• impurities: ≤0.5 ppm As (Arsenic), ≤0.5 ppm Cd (Cadmium), ≤0.5 ppm Co (Cobalt), ≤0.5 ppm Cu (Copper), ≤0.5 ppm Mn (Manganese), ≤0.5 ppm Pb (Lead), ≤1 ppm Fluoride (F), ≤1.0 ppm Ni (Nickel), ≤10 ppm Fe (Iron), ≤10 ppm Heavy metals (as Pb), ≤10 ppm Insoluble matter, ≤10 ppm Substances reducing potassium permanganate (as O), ≤10 ppm Volatile acids (as Acetic acid), ≤2 ppm Chloride (Cl), ≤2 ppm Zn (Zinc), ≤20 ppm Ca (Calcium), ≤20 ppm Phosphite and Hypophosphite (as H₃PO₃), ≤20 ppm Sulfate (SO₄), ≤200 ppm Na (Sodium), ≤3 ppm Nitrate (NO₃), ≤5 ppm K (Potassium), ≤5 ppm Mg (Magnesium), ≤5 ppm Sb (Antimony)
• color: APHA: ≤10
• pH: <0.5 (20 °C, 100 g/L in H₂O)
• kinematic viscosity: 30.5 cSt(20 °C)
• bp: 158 °C (lit.)
• mp: ~40 °C (lit.)
• density: 1.685 g/mL at 25 °C (lit.)
• greener alternative category: Enabling
• SMILES string: OP(O)(O)=O
• storage temp.: no temp limit
• InChI: 1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)
• InChI key: NBIIXXVUZAFLBC-UHFFFAOYSA-N

Description

General description

pour analyse EMSURE^® ACS, ISO, Réact. Ph. Eur.

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Application

ortho-Phosphoric acid can be used as a:

• Reactant in the synthesis of polyurethane ionomer films through etherification with polyoxypropylene glycol in the presence of tertiary amines.
• Catalyst in pinacolic rearrangement reactions when it is supported on silica.
• Phosphorus source in the synthesis of diaryl phosphates.

Analysis Note

Test (alcalimétrique)≥ 85,0 %Identitésatisfait au testApparence de la solutionsatisfait au testCouleur≤ 10 HazenChlorure (Cl)≤ 2 ppmFluorure (F)≤ 1 ppmNitrate (NO₃)≤ 3 ppmPhosphite et hypophosphite (exprimé en H₃PO₃)≤ 20 ppmHypophosphite, phosphitesatisfait au testMétaux lourds (exprimé en Pb)≤ 10 ppmSulfate (SO₄)≤ 20 ppmAs (arsenic)≤ 0,5 ppmCa (calcium)≤ 20 ppmCd (cadmium)≤ 0,5 ppmCo (cobalt)≤ 0,5 ppmCu (cuivre)≤ 0,5 ppmFe (fer)≤ 10 ppmK (potassium)≤ 5 ppmMg (magnésium)≤ 5 ppmMn (manganèse)≤ 0,5 ppmNa (sodium)≤ 200 ppmNi (nickel)≤ 1,0 ppmPb (plomb)≤ 0,5 ppmSb (antimoine)≤ 5 ppmZn (zinc)≤ 2 ppmSubstances précipitées par l′ammoniacsatisfait au testAcides volatils (sous forme d′acide acétique)≤ 10 ppmSubstances réduisant le permanganate de potassium (sous forme d′O)≤ 10 ppmMatière insoluble≤ 10 ppm

Other Notes

L′acide phosphorique concentré est composé de H₃PO₄ à environ 85 % (aqueux).

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• pictograms: GHS05,GHS07
• signalword: Danger
• pcodes: P234 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
• flash_point_f: does not flash
• flash_point_c: does not flash
• hcodes: H290,H302,H314
• Classe de stockage: 8B - Non-combustible corrosive hazardous materials