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C19651

Chloroacetonitrile

99%

Synonyme(s) :

α-Chloroacetonitrile, 2-Chloroacetonitrile, Chloromethyl cyanide, Cyanomethyl chloride, Monochloroacetonitrile

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A propos de cet article

Formule linéaire :
ClCH2CN
Numéro CAS:
Poids moléculaire :
75.50
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-467-0
Beilstein/REAXYS Number:
506028
MDL number:
Assay:
99%
Form:
liquid
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vapor density

3 (vs air)

Quality Segment

vapor pressure

1.78 psi ( 20 °C)

assay

99%

form

liquid

refractive index

n20/D 1.422 (lit.)

bp

124-126 °C (lit.)

density

1.193 g/mL at 25 °C (lit.)

functional group

nitrile

SMILES string

ClCC#N

InChI

1S/C2H2ClN/c3-1-2-4/h1H2

InChI key

RENMDAKOXSCIGH-UHFFFAOYSA-N

Application

Chloroacetonitrile can be used:
  • For the synthesis of ionic liquids containing nitrile functionalized imidazolium salts.
  • For the synthesis of cyanomethyl dodecyl trithiocarbonate, a reversible addition-fragmentation chain transfer (RAFT) agent.
  • As an alkylating reagent for the synthesis of derivatives of triazolyl thiazoles to be used as anti-tuberculosis agents.
  • As a reagent in photo Meerwein addition reaction for amino-arylation of alkenes.
  • As an esterifying agent in the synthesis of a cytotoxic natural product: apicularen A.


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Cet article
125954678872372978
assay

99%

assay

98%

assay

98% (CP)

assay

≥99%

bp

124-126 °C (lit.)

bp

110-112 °C (lit.)

bp

-

bp

60.5-61.5 °C (lit.)

density

1.193 g/mL at 25 °C (lit.)

density

1.369 g/mL at 25 °C (lit.)

density

-

density

1.48 g/mL at 25 °C, 1.492 g/mL at 25 °C (lit.)

form

liquid

form

liquid

form

-

form

liquid

refractive index

n20/D 1.422 (lit.)

refractive index

n20/D 1.44 (lit.)

refractive index

-

refractive index

n20/D 1.445 (lit.)

vapor pressure

1.78 psi ( 20 °C)

vapor pressure

-

vapor pressure

-

vapor pressure

160 mmHg ( 20 °C)


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signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3

Classe de stockage

3 - Flammable liquids

wgk

WGK 3

flash_point_f

129.2 °F

flash_point_c

54 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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