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775118

Sigma-Aldrich

Borane dimethyl sulfide complex solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

Synonyme(s) :

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Formule linéaire :
(CH3)2S · BH3
Numéro CAS:
13292-87-0
Poids moléculaire :
75.97
Numéro Beilstein :
3663489
Numéro MDL:
MFCD00013189
Code UNSPSC :
12352112
ID de substance PubChem :
329767736
Nomenclature NACRES :
NA.22

Forme

liquid

Pertinence de la réaction

reagent type: reductant

Caractéristiques du produit alternatif plus écologique

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Concentration

1.0 M in 2-methyltetrahydrofuran

Densité

0.844 g/mL at 25 °C

Autre catégorie plus écologique

, Aligned

Température de stockage

2-8°C

Chaîne SMILES 

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

Clé InChI

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Application

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane
Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Conditionnement

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Informations légales

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

Risques supp

EUH019

Code de la classe de stockage

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

9.3 °F

Point d'éclair (°C)

-12.6 °C

Certificats d'analyse (COA)

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