241911

Tungsten(VI) chloride

≥99.9% trace metals basis

• Synonyme(s) : Tungsten hexachloride
• Formule linéaire : WCl₆
• Numéro CAS: 13283-01-7
• Poids moléculaire : 396.56
• Numéro CE : 236-293-9
• Numéro MDL: MFCD00011463
• Code UNSPSC : 12352302
• ID de substance PubChem : 24854501
• Nomenclature NACRES : NA.23

Propriétés

• Pression de vapeur: 43 mmHg ( 215 °C)
• Niveau de qualité: 100
• Pureté: ≥99.9% trace metals basis
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; core: tungsten
• Impuretés: ≤1000.0 ppm Trace Metal Analysis
• Point d'ébullition: 347 °C (lit.)
• Pf: 275 °C (lit.)
• Densité: 3.52 g/mL at 25 °C (lit.)
• Chaîne SMILES: Cl[W](Cl)(Cl)(Cl)(Cl)Cl
• InChI: 1S/6ClH.W/h6*1H;/q;;;;;;+6/p-6
• Clé InChI: KPGXUAIFQMJJFB-UHFFFAOYSA-H

Description

Description générale

Tungsten(VI) chloride is a highly reactive crystalline solid commonly used in the field of catalysis, perovskite solar cells, and light-emitting devices. It is a diamagnetic solid. However, it can be highly corrosive and have strong oxidizing effects.

Application

Tungsten(VI) chloride can be used:

• As a starting material to synthesize tungsten nanoparticles and Mo-doped urchin-like W₁₈O₄₉ Nanostructure using the hydrothermal method. The Mo-W₁₈O₄₉ electrocatalyst exhibited excellent electrocatalytic activity toward Hydrogen Evolution Reaction (HER). By doping Mo species into defect-rich W₁₈O₄₉ ultrathin nanowires, it has also been demonstrated to be an excellent candidate for photocatalytic N₂ fixation to ammonia.
• To synthesize crystalline mesoporous WO₃ with 11 nm pore size utilizing a high-molecular-weight amphiphilic block copolymer as the structure-directing agent. The materials performed admirably in terms of H₂S gas sensing.
• To fabricate Tungsten disulfide and WS₂/reduced graphene oxide (WS₂/rGO) nanosheets by hydrothermal synthesis. The WS₂/rGO nanosheets showed exceptional electrocatalytic activity for the hydrogen evolution reaction.
• To produce the WS₂-nanoflowers@rGO and nitrogen-doped carbon spheres@WS₂ composite as an anode material for enhanced electrode performance in lithium-ion batteries.
• As a dopant to fabricate TiO₂ compact layers for perovskite solar cells with enhanced performance.
• As a catalyst to prepare self-healing epoxy composites with microcapsules.
• As a catalyst for transamidation of tertiary alkyl amides.

Informations sur la sécurité

• Pictogrammes: GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H314,H335,H412
• Conseils de prudence: P260 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 8A - Combustible corrosive hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges