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C6882

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Cinchonine hemisulfate salt

analytical standard

Synonyme(s) :

Cinchonan-9(S)-ol hemisulfate salt

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About This Item

Formule linéaire :
C19H22N2O · 1/2H2SO4
Numéro CAS:
5949-16-6
Poids moléculaire :
343.43
Numéro CE :
227-708-4
Numéro MDL:
MFCD00035639
Code UNSPSC :
41116107
ID de substance PubChem :
329775136

Qualité

analytical standard

Niveau de qualité

100

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

food and beverages

Format

neat

Chaîne SMILES 

OS(O)(=O)=O.O[C@H]([C@H]1C[C@@H]2CCN1C[C@@H]2C=C)c3ccnc4ccccc34.O[C@H]([C@H]5C[C@@H]6CCN5C[C@@H]6C=C)c7ccnc8ccccc78

InChI

1S/2C19H22N2O.H2O4S/c2*1-2-13-12-21-10-8-14(13)11-18(21)19(22)16-7-9-20-17-6-4-3-5-15(16)17;1-5(2,3)4/h2*2-7,9,13-14,18-19,22H,1,8,10-12H2;(H2,1,2,3,4)/t2*13-,14-,18+,19-;/m00./s1

Clé InChI

WBBHOISPYYYBTC-SJFRDBBCSA-N

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
048F0867

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Consulter la Bibliothèque de documents

Péter Király et al.
Magnetic resonance in chemistry : MRC, 48(1), 13-19 (2009-10-29)
The conformational diversity of the (3R,4S,8R,9R)-9-[(3,5-bis(trifluoromethyl)phenyl))-thiourea](9-deoxy)-epi-cinchonine organocatalyst is discussed. Low-temperature NMR experiments confirmed a self-association process, which promotes the quinoline rotation between two intramolecularly hydrogen-bonded monomeric conformers of the catalyst. The balanced population of the coexisting monomeric and dimeric species
Hirdyesh Mishra et al.
Journal of fluorescence, 18(1), 17-27 (2007-08-24)
Photo induced excited state dynamical processes of cinchonine alkaloid dication (C(++)) have been studied over a wide range of temperature using steady state and nanosecond time-resolved fluorescence spectroscopic techniques. The temperature-dependent fluorescence studies of C(++) clearly indicate the existence of
Aleksandra Wesełucha-Birczyńska et al.
Chirality, 22(6), 557-564 (2009-11-04)
Studies on the interactions between L-O- phosphoserine, as one of the simplest fragments of membrane components, and the Cinchona alkaloid cinchonine, in the crystalline state were performed. Cinchoninium L-O-phosposerine salt dihydrate (PhSerCin) crystallizes in a monoclinic crystal system, space group
Jiabing Jiang et al.
Journal of chromatography. A, 1218(24), 3763-3770 (2011-05-11)
We designed and synthesized a cinchonine derivative to be used as a novel chiral monomer. It was employed in a dual role of functional monomer and cross-linking monomer, displaying multi-binding sites for the template (S)-ketoprofen. Monodisperse molecularly imprinted core-shell microspheres
Wei Chen et al.
Organic & biomolecular chemistry, 5(5), 816-821 (2007-02-23)
The C3-selective enantioselective Michael-type Friedel-Crafts alkylations of indoles with nonchelating alpha,beta-unsaturated alkyl ketones, catalysed by a chiral primary amine derived from natural cinchonine, were investigated. The reactions, in the presence of 30 mol% catalyst, were smoothly conducted at 0 to
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