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Isopyrazam

PESTANAL®, analytical standard, mixture of isomers

Synonyme(s) :

3-(Difluoromethyl)-1-methyl-N-[1,2,3,4-tetrahydro-9-(1-methylethyl)-1,4-methanonaphthalen-5-yl]-1H-pyrazole-4-carboxamide

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About This Item

Formule empirique (notation de Hill):
C20H23F2N3O
Numéro CAS:
881685-58-1
Poids moléculaire :
359.41
Code UNSPSC :
41116107
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

100

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
environmental

Format

neat

Chaîne SMILES 

CC(C)C1C2CCC1c3c(NC(=O)c4cn(C)nc4C(F)F)cccc23

InChI

1S/C20H23F2N3O/c1-10(2)16-12-7-8-13(16)17-11(12)5-4-6-15(17)23-20(26)14-9-25(3)24-18(14)19(21)22/h4-6,9-10,12-13,16,19H,7-8H2,1-3H3,(H,23,26)

Clé InChI

XTDZGXBTXBEZDN-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Isopyrazams are categorized under the class of succinate-dehydrogenase-inhibitor (SDHI) fungicides that are applied on a variety of fruits and vegetables.

Application

Isopyrazam may be used as an analytical reference standard for the determination of the analyte in:
  • Honeybees by dispersive solid-phase extraction (dSPE), followed by liquid and gas chromatography combined with tandem mass spectrometry (LC-MS/MS and GC-MS/MS) operating in electron ionization (EI) and multiple reaction monitoring (MRM) modes of detection.
  • Bee pollen samples by GC-MS/MS in single reaction monitoring (SRM) mode of detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Health hazardExclamation markEnvironment
GHS08,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H317,H351,H360D,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Repr. 1B - Skin Sens. 1B

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Choose from one of the most recent versions:

Certificats d'analyse (COA)

Lot/Batch Number
BCCF6964
BCBS8691V
SZBF098XV
SZBD178XV
SZB9307XV

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If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

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Multi-residue method for the determination of pesticides and pesticide metabolites in honeybees by liquid and gas chromatography coupled with tandem mass spectrometry?Honeybee poisoning incidents.
Kiljanek T, et al.
Journal of Chromatography A, 1435(14), 100-114 (2016)
A sensitive and efficient method for routine pesticide multiresidue analysis in bee pollen samples using gas and liquid chromatography coupled to tandem mass spectrometry.
Vazquez PP, et al.
Journal of Chromatography A, 1426(14), 161-173 (2015)
Khuram Shahzad Ahmad et al.
Journal of basic microbiology, 60(6), 484-493 (2020-04-22)
The current research is a pioneer in the evaluation of isopyrazam biodegradation, which has been performed utilizing soil-isolated microbes. Biodisintegrative assays of pure fungal strains, namely Aspergillus flavus (AF), Penicillium chrysogenum (PC), Aspergillus niger (AN), Aspergillus terreus (AT), and Aspergillus
Zhaobin Mu et al.
Analytical and bioanalytical chemistry, 408(5), 1515-1522 (2015-12-31)
A multi-residue method based on modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) sample preparation, followed by liquid chromatography tandem mass spectrometry (LC-MS/MS), was developed and validated for the determination of three selected fungicides (propiconazole, pyraclostrobin, and isopyrazam) in
M Masiello et al.
International journal of food microbiology, 334, 108799-108799 (2020-08-18)
Aspergillus flavus is a common and ubiquitous fungal species able to colonize several agricultural commodities, in both pre- and post-harvest conditions. This species represents a very harmful plant pathogen for its ability to synthesize aflatoxin B1, responsible for human primary
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