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Folpet

PESTANAL®, analytical standard

Synonyme(s) :

2-(Trichloromethylsulfanyl)isoindole-1,3-dione

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About This Item

Formule empirique (notation de Hill):
C9H4Cl3NO2S
Numéro CAS:
133-07-3
Poids moléculaire :
296.56
Numéro Beilstein :
193373
Numéro CE :
205-088-6
Numéro MDL:
MFCD00047303
Code UNSPSC :
41116107
ID de substance PubChem :
329753988
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

100

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

Format

neat

Chaîne SMILES 

ClC(Cl)(Cl)SN1C(=O)c2ccccc2C1=O

InChI

1S/C9H4Cl3NO2S/c10-9(11,12)16-13-7(14)5-3-1-2-4-6(5)8(13)15/h1-4H

Clé InChI

HKIOYBQGHSTUDB-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Folpet is a contact fungicide used for the control of foliar and seed-borne diseases. Folpet is known to inhibit various oxidative enzymes, carboxylases and also enzymes required for phosphate metabolism and citrate synthesis.

Application

Folpet may be used as a reference standard for the determination of the analyte in food matrices based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) method for extraction followed by gas chromatography coupled with electron ionization and triple quadrupole mass spectrometry (GC-EI-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Produits recommandés

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Health hazardExclamation markEnvironment
GHS08,GHS07,GHS09

Mention d'avertissement

Warning

Mentions de danger

H317,H319,H332,H351,H400

Classification des risques

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Skin Sens. 1

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
BCCL4579
BCCJ0793
BCCD1736
BCCD0436
BCBX4657

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If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

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Quantification of folpet and phthalimide in food by gas chromatography and mass spectrometry: Overcoming potential analytical artefacts.
Huertas-Perez JF, et al.
Food Chemistry, 260, 213-220 (2018)
Mireille Canal-Raffin et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 865(1-2), 106-113 (2008-03-18)
Solid-phase extractions followed by HPLC-UV/DAD methods were developed for occupational biological monitoring or forensic investigations of the fungicide folpet using its degradation products, phthalimide and phthalamic acid as plasma biomarkers. These methods show good linearity (r>0.9955), precision (CV<15%) and accuracy
Mireille Canal-Raffin et al.
Toxicology, 249(2-3), 160-166 (2008-07-01)
Folpet, a widely used dicarboximide fungicide, has been detected in the ambient air of several vine-growing regions of France. It is present in particle form in the environment; however, no study exploring its potential health impact on airways and the
Samuel M Cohen et al.
Critical reviews in toxicology, 40(6), 531-545 (2010-06-05)
A framework has been evolving for evaluation of mode of action (MOA) of rodent toxicity and carcinogenicity findings and their relevance to humans. Folpet produces duodenal glandular tumors in mice, but is not carcinogenic in rats. A wealth of information
Shuju Wang et al.
Se pu = Chinese journal of chromatography, 25(2), 226-229 (2007-06-22)
A method for the simultaneous determination of captan and folpet pesticide residues in apples was developed by solid-phase extraction and high performance liquid chromatography. The sample was extracted with acetonitrile and cleaned-up by a mixture of homemade sorbent and silica
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