808024

(S,R,R)-Elenor Amination Reagent

• Synonyme(s) : 3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
• Formule empirique (notation de Hill): C₁₁H₁₈N₂O₄S
• Numéro CAS: 139331-02-5
• Poids moléculaire : 274.34
• Code UNSPSC : 12352000
• ID de substance PubChem : 329769052
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder
• Niveau de qualité: 100
• Température de stockage: 2-8°C
• Chaîne SMILES: O=C(N1S(C[C@]2(C3(C)C)CC[C@]3([H])C[C@@]12[H])(=O)=O)NO
• InChI: 1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m1/s1
• Clé InChI: FYSORZDAOUCPGD-SOCHQFKDSA-N

Description

Application

The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air.

Autres remarques

Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable