692336

RUCL₂[(R)(DM−SEGPHOS)][(R,(R))(DPEN)]

• Synonyme(s) : Dichloro[(R)−5,5′−bis[di(3,5−xylyl)phosphino]−4,4′−bi−1,3−benzodioxole][1R,2R−1,2−diphenylethylenediamine]ruthenium(ΙΙ)
• Formule empirique (notation de Hill): C₆₀H₆₀Cl₂N₂O₄P₂Ru
• Numéro CAS: 944450-45-7
• Poids moléculaire : 1107.05
• Numéro MDL: MFCD09753031
• Code UNSPSC : 12352005
• ID de substance PubChem : 329761484
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder
• Température de stockage: 2-8°C
• Chaîne SMILES: Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
• InChI: 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• Clé InChI: FOEKPXQPRAIJRW-ODQAEMFESA-L

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.

Informations légales

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 JP Application No. 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable