Controlled introduction of proton transfer into the design of a series of molecular complexes is described, delivering the systematic production of ionic molecular complexes (molecular salts). The controlled production of molecular salts has relevance as a potential strategy in the
Synthesis of 2, 2'-Bipyridines: Versatile Building Blocks for Sexy Architectures and Functional Nanomaterials.
European Journal of Organic Chemistry, 2, 235-254 (2004)
Copper (ii) complexes of 2-halo-3-methylpyridine: synthesis, structure, and magnetic behaviour of Cu (2-X-3-CH 3 py) 2 X' 2 [X, X'= chlorine or bromine; py= pyridine].
[reaction: see text] The scope and limitations of the conjugate addition of 2- and the first 4-pyridyl Gilman homocuprates to various alpha,beta-unsaturated Michael acceptors are delineated. The conjugate addition of the cuprate of 2-bromo-3-methylpyridine to (E)-methyl crotonate then diastereoselective enolate
The Journal of organic chemistry, 67(6), 1838-1842 (2002-03-16)
2,2'-Bipyridine (bpy) and a series of dimethyl-2,2'-bipyridines were synthesized from 2-bromopyridine and 2-bromomethylpyridines, respectively, using an electrochemical process catalyzed by nickel complexes. The method is simple and efficient, with isolated yields between 58 and 98% according to the structure. We
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