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2-Bromo-1,10-phenanthroline

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About This Item

Empirical Formula (Hill Notation):

C₁₂H₇BrN₂

CAS Number:

22426-14-8

Molecular Weight:

259.10

NACRES:

NA.22

PubChem Substance ID:

329768737

UNSPSC Code:

12352100

MDL number:

MFCD13152102

Form:

powder

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Properties

form

powder

Quality Segment

100

mp

160-165 °C

functional group

bromo

SMILES string

BrC1=NC2=C(N=CC=C3)C3=CC=C2C=C1

InChI

1S/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H

InChI key

ZRJUDAZGVGIDLP-UHFFFAOYSA-N

Description

Application

Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Other Notes

Regioselective Bromination of Fused Heterocyclic N-Oxides

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This Item	301817	678015	301779
Sigma-Aldrich 802425 2-Bromo-1,10-phenanthroline	Sigma-Aldrich 301817 5,6-Dimethyl-1,10-phenanthroline	Sigma-Aldrich 678015 4,7-Dichloro-1,10-phenanthroline	Sigma-Aldrich 301779 5-Chloro-1,10-phenanthroline
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
form powder	form -	form solid	form -
mp 160-165 °C	mp 266-269 °C (lit.)	mp 243-247 °C	mp 124-126 °C (lit.)
functional group bromo	functional group -	functional group -	functional group chloro

pictograms

GHS06,GHS05,GHS09

signalword

Danger

hcodes

H301,H315,H318,H410

pcodes

P273 - P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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