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301817

Sigma-Aldrich

5,6-Dimethyl-1,10-phenanthroline

97%

Synonym(s):

5,6-Dimethyl-o-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C14H12N2
CAS Number:
3002-81-1
Molecular Weight:
208.26
Beilstein:
160918
EC Number:
221-100-2
MDL number:
MFCD00004983
UNSPSC Code:
12352100
PubChem Substance ID:
24858212
NACRES:
NA.22

Quality Level

100

Assay

97%

mp

266-269 °C (lit.)

SMILES string

Cc1c(C)c2cccnc2c3ncccc13

InChI

1S/C14H12N2/c1-9-10(2)12-6-4-8-16-14(12)13-11(9)5-3-7-15-13/h3-8H,1-2H3

InChI key

BRPQDJPJBCQFSR-UHFFFAOYSA-N

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Application

5,6-Dimethyl-1,10-phenanthroline was employed as ligand in the preparation of:
  • novel tetrahedral copper(I) mixed-ligand complexes
  • mixed ligand Ru(II) complexes
  • 5,6-bis(bromomethyl)-1,10-phenanthroline via bromination with N-bromosuccinimide

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Valentina Gandin et al.
Journal of medicinal chemistry, 56(18), 7416-7430 (2013-08-24)
Novel tetrahedral copper(I) mixed-ligand complexes of the type [Cu(X)(N(∩)N)(PCN)], 3-10, where X = Cl or Br, N(∩)N = 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 5,6-dimethyl-1,10-phenanthroline (dmp), and dipyrido-[3,2-d:2',3'-f]-quinoxaline (dpq), and PCN = tris-(2-cyanoethyl)phosphine, have been synthetized and characterized by NMR, ESI-MS, and
Self-assembled fullerene-derivative monolayers on a gold substrate using phenanthroline-Au interactions.
Dominguez O, et al.
Langmuir, 14(4), 821-824 (1998)
Mixed ligand ruthenium (II) complexes of 5, 6-dimethyl-1, 10-phenanthroline: the role of ligand hydrophobicity on DNA binding of the complexes.
Uma MP, et al.
Inorgorganica Chimica Acta, 359(14), 4601-4612 (2006)

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