Chemical & pharmaceutical bulletin, 57(11), 1179-1188 (2009-11-03)
This review describes our recent efforts in the development of chiral dinuclear vanadium complexes which work as dual activation catalysts for oxidative coupling of 2-naphthols. A chiral dinuclear vanadium(IV) complex (R(a),S,S)-1a possessing (S)-tert-leucine moieties at the 3,3'-positions of the (R)-binaphthyl
The Journal of biological chemistry, 284(28), 18577-18581 (2009-04-14)
Nature has developed an exquisite array of methods to introduce halogen atoms into organic compounds. Most of these enzymes are oxidative and require either hydrogen peroxide or molecular oxygen as a cosubstrate to generate a reactive halogen atom for catalysis.
Journal of inorganic biochemistry, 102(5-6), 1152-1158 (2008-02-08)
In the present focused review, vanadate-dependent haloperoxidases and vanadate-inhibited enzymes which catalyze the hydrolysis of phosphoester bonds are addressed. In these systems, vanadate [HxVO4](3-x)(-) is covalently coordinated to the imidazolyl moiety of an active site histidine, with a geometrical arrangement
QJM : monthly journal of the Association of Physicians, 101(5), 351-358 (2008-03-06)
To assess the effectiveness of oral vanadium supplementation for glycaemic control in type 2 diabetes by conducting a systematic review of the literature. Eligible studies were identified by searching 14 databases using standardized terms. Experts, study authors and manufacturers were
Canadian journal of physiology and pharmacology, 82(10), 833-839 (2004-12-02)
Inorganic and organic compounds of vanadium have been shown to exhibit a large range of insulinomimetic effects in the cardiovascular system, including stimulation of glucose transporter 4 (GLUT-4) translocation and glucose transport in adult cardiomyocytes. Furthermore, administration of vanadium compounds
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