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Merck

Lipase catalyzed synthesis of benzyl acetate in solvent-free medium using vinyl acetate as acyl donor.

Bioorganic & medicinal chemistry letters (2006-05-23)
Abir B Majumder, Bhupender Singh, Debjit Dutta, Sushabhan Sadhukhan, Munishwar N Gupta
RESUMO

Use of vinyl acetate as acyl donor in transesterification of benzyl alcohol catalyzed by a commercially available lipase (Lipozyme RM IM) gave 100% conversion in 10 min. The excess acyl donor and the enzyme could be recovered and reused. Unlike the chemical catalytic processes, it produced no undesirable side product.

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Sigma-Aldrich
Benzyl acetate, ≥99%
Sigma-Aldrich
Benzyl acetate, ≥99%, FCC, FG
Sigma-Aldrich
Benzyl acetate, natural, ≥99%, FCC, FG
Supelco
Benzyl acetate, analytical standard