CRM52554
Spiroxamine
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonyme(s) :
N-Ethyl-N-propyl-8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-ylmethylamine
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About This Item
Formule empirique (notation de Hill):
C18H35NO2
Numéro CAS:
Poids moléculaire :
297.48
Numéro MDL:
Code UNSPSC :
41116107
Nomenclature NACRES :
NA.24
Produits recommandés
Qualité
certified reference material
TraceCERT®
Niveau de qualité
Gamme de produits
TraceCERT®
Durée de conservation
limited shelf life, expiry date on the label
Fabricant/nom de marque
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Format
neat
Température de stockage
2-8°C
Chaîne SMILES
CCCN(CC)CC1COC2(CCC(CC2)C(C)(C)C)O1
InChI
1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-16H,6-14H2,1-5H3
Clé InChI
PUYXTUJWRLOUCW-UHFFFAOYSA-N
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Description générale
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The spiroxamine CRM may also find the following uses:
The spiroxamine CRM may also find the following uses:
- Development of an enantioselective method to determine three fungicide residues in grapevine, sugar beet, and wheat samples by gas chromatography-tandem mass spectrometry (GC-MS/MS)
- Quantification of 19 neonicotinoids and fungicides from pollen and individual bumblebee samples using modified QuEChERS extraction with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)
- Evaluation of a gas chromatographic method with electron capture and nitrogen phosphorus detection (GC/ECD/NPD) for the analysis of 46 pesticides in fresh peppermint samples
- Multi-residue determination of 25 pesticide residues in red wine by gas chromatography-mass spectrometry(GC-MS)
- QuEChERS extraction and liquid chromatography-tandem mass spectrometry based determination of 42 pesticides in six marijuana samples
- Investigation of three different sample preparation methods to select the most suitable one for the analysis of 98 pesticides in globe artichoke leaves and fruit samples by LC-MS and GC-MS
Informations légales
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Mention d'avertissement
Warning
Mentions de danger
Classification des risques
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2
Organes cibles
Eyes
Code de la classe de stockage
10 - Combustible liquids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
296.6 °F
Point d'éclair (°C)
147 °C
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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.
Andrea Kunova et al.
Microorganisms, 9(7), 1541-1541 (2021-08-08)
Grapevine powdery mildew is a principal fungal disease of grapevine worldwide. Even though it usually does not cause plant death directly, heavy infections can lead to extensive yield losses, and even low levels of the disease can negatively affect the
Ignaz J Buerge et al.
Journal of agricultural and food chemistry, 64(26), 5301-5309 (2016-06-02)
Metabolism of chiral pesticides in crops is typically studied using achiral analytical methods and, consequently, the stereoisomer composition of residues is unknown. In this study, we developed an enantioselective GC-MS/MS method to quantify residues of the fungicides fenpropidin, fenpropimorph, and
Arthur David et al.
Analytical and bioanalytical chemistry, 407(26), 8151-8162 (2015-09-04)
To accurately estimate exposure of bees to pesticides, analytical methods are needed to enable quantification of nanogram/gram (ng/g) levels of contaminants in small samples of pollen or the individual insects. A modified QuEChERS extraction method coupled with ultra-high-performance liquid chromatography
Validation of a QuEChERS-based gas chromatographic method for multiresidue pesticide analysis in fresh peppermint including studies of matrix effects
Slowik-Borowiec M
Food Analytical Methods, 8(6), 1413-1424 (2015)
Maja Pelajić et al.
Food chemistry, 200, 98-106 (2016-02-03)
A new multiresidue method was developed for determination of 25 pesticide residues in red wine by gas chromatography coupled to mass spectrometry with a single run of 23.63 min. Samples were extracted from wine with solid phase extraction using Oasis
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