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310700

Sigma-Aldrich

Manganese(IV) oxide

10 μm, reagent grade, ≥90%

Synonyme(s) :

Manganese dioxide

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About This Item

Formule empirique (notation de Hill):
MnO2
Numéro CAS:
1313-13-9
Poids moléculaire :
86.94
Numéro CE :
215-202-6
Numéro MDL:
MFCD00003463
Code UNSPSC :
12352303
ID de substance PubChem :
329753639
Nomenclature NACRES :
NA.55

Qualité

reagent grade

Pureté

≥90%

Forme

powder

Taille des particules

10 μm

Pf

535 °C (dec.) (lit.)

Chaîne SMILES 

O=[Mn]=O

InChI

1S/Mn.2O

Clé InChI

NUJOXMJBOLGQSY-UHFFFAOYSA-N

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Description générale

Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions.

Application


  • High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018).


  • Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).


Pictogrammes

Health hazardExclamation mark
GHS08,GHS07

Mention d'avertissement

Warning

Mentions de danger

H302 + H332,H373

Classification des risques

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation

Organes cibles

Brain

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

does not flash

Point d'éclair (°C)

does not flash

Certificats d'analyse (COA)

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Cahiez G, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Y Wang et al.
Journal of colloid and interface science, 380(1), 8-15 (2012-06-02)
Bio-inspired chemical approach has been developed for the surface modification and electrophoretic deposition of manganese dioxide and zirconia nanoparticles, prepared by chemical precipitation methods. Caffeic acid, trans-cinnamic acid, p-coumaric acid, and 2,4-dihydroxycinnamic acid were investigated for the surface modification of
Michael K L Chu et al.
Lab on a chip, 12(14), 2533-2539 (2012-05-09)
We have developed glucose-responsive implantable microdevices for closed-loop delivery of insulin and conducted in vivo testing of these devices in diabetic rats. The microdevices consist of an albumin-based bioinorganic membrane that utilizes glucose oxidase (GOx), catalase (CAT) and manganese dioxide
Wen-Hui Kuan et al.
Journal of hazardous materials, 239-240, 152-159 (2012-09-25)
This study examined the reaction of methylene blue (MB) with tunneled manganese oxide pyrolusite regarding pH and reaction time. MB was cleaved through N-demethylation, in which reaction azure B (AB), azure A (AA), azure C (AC), and thionin (TH) were
Xin Zhao et al.
ACS nano, 6(6), 5404-5412 (2012-05-05)
Manganese dioxide (MnO(2)) particles 2-3 nm in size were deposited onto a porous "activated microwave expanded graphite oxide" (aMEGO) carbon scaffold via a self-controlled redox process. Symmetric electrochemical capacitors were fabricated that yielded a specific capacitance of 256 F/g (volumetric:
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