W379401

(3aR)-(+)-Sclareolide

natural, 97%, FG

• Synonyme(s) : Sclareolide
• Formule empirique (notation de Hill): C₁₆H₂₆O₂
• Numéro CAS: 564-20-5
• Poids moléculaire : 250.38
• Numéro FEMA: 3794
• Numéro CE : 209-269-0
• Numéro MDL: MFCD00134168
• Code UNSPSC : 12164502
• ID de substance PubChem : 329830654
• Numéro Flavis : 16.055
• Nomenclature NACRES : NA.21

Propriétés

• Source biologique: Salvia sclarea L
• Niveau de qualité: 400
• Qualité: FG; Fragrance grade; natural
• Agence: follows IFRA guidelines
• Conformité réglementaire: EU Regulation 1223/2009; EU Regulation 1334/2008 & 872/2012; FDA 21 CFR 110
• Pureté: 97%
• Caractéristiques du produit alternatif plus écologique: Less Hazardous Chemical Syntheses; Use of Renewable Feedstocks; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Impuretés: may contain ≤0.10% 2-Methylpentane (residual solvent)
• Pf: 124-126 °C (lit.)
• Application(s): flavors and fragrances
• Documentation: see Safety & Documentation for available documents
• Allergène alimentaire: no known allergens
• Allergène de parfum: sclareol
• Autre catégorie plus écologique: Aligned
• Propriétés organoleptiques: woody; paper
• Chaîne SMILES: [H][C@@]12CC[C@@]3(C)OC(=O)C[C@]3([H])[C@@]1(C)CCCC2(C)C
• InChI: 1S/C16H26O2/c1-14(2)7-5-8-15(3)11(14)6-9-16(4)12(15)10-13(17)18-16/h11-12H,5-10H2,1-4H3/t11-,12+,15-,16+/m0/s1
• Clé InChI: IMKJGXCIJJXALX-SHUKQUCYSA-N

Description

Description générale

We are committed to bringing you greener alternative products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is Biobased and thus aligns with "Less Hazardous Chemical Syntheses" and "Use of Renewable Feedstocks".

Application

• Approach to Merosesquiterpenes via Lewis Acid Catalyzed Nazarov-Type Cyclization.: The synthesis of "(3aR)-(+)-Sclareolide" plays a crucial role in the total synthesis of Akaol A, a merosesquiterpene. This compound is utilized in studies focusing on Lewis acid-catalyzed Nazarov-type cyclization, which is a key reaction for constructing complex cyclic structures within organic molecules. This synthesis process not only expands the capabilities of chemists to build intricate molecular architectures but also enhances the understanding of reaction mechanisms crucial for pharmaceutical development (DOI: 10.1021/acs.orglett.6b00446).

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)