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146617

Sigma-Aldrich

Bathophenanthrolinedisulfonic acid disodium salt hydrate

98%

Synonym(s):

Bathophenanthrolinedisulfonic acid disodium salt trihydrate, 4,7-Diphenyl-1,10-phenanthroline-disulfonic acid disodium salt trihydrate, Disodium bathophenanthrolinedisulfonate trihydrate

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About This Item

Empirical Formula (Hill Notation):
C24H14N2Na2O6S2 · 3H2O
CAS Number:
52746-49-3
Molecular Weight:
590.53
EC Number:
258-152-0
UNSPSC Code:
12352100
NACRES:
NA.22

Quality Level

100

Assay

98%

form

powder

mp

300 °C

solubility

water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)

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General description

Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.

Application

Bathophenanthrolinedisulfonic acid disodium salt hydrate was used in the preparation of anionic Europium(III) disulfonated bathophenanthroline tris(dibenzoylmethanate) complex.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Intercalation of luminescent Europium (III) complexes in layered double hydroxides.
Sarakha L, et al.
Opt. Mater., 31(3), 562-566 (2009)
Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)
Elizabeth M Zammit et al.
The Analyst, 136(15), 3069-3072 (2011-06-29)
The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.
Yan-Zhong Chang et al.
Molecular pharmacology, 69(3), 968-974 (2005-12-01)
Based on the available data, we speculated that changes in brain iron metabolism induced by L-DOPA might be associated with the neurotoxicity of L-DOPA. To investigate this possibility, the effects of L-DOPA on the expression of iron influx proteins [transferrin
A Paolicchi et al.
Journal of investigative medicine : the official publication of the American Federation for Clinical Research, 47(3), 151-160 (1999-04-13)
gamma-Glutamyl transpeptidase (gamma-GT) is found in serum and in the plasma membranes of virtually all cell types. Its physiologic role is to initiate the hydrolysis of extracellular glutathione (GSH), a tripeptide in which cysteine lies between alpha-glycine and gamma-glutamate residues.
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