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243361

Sigma-Aldrich

Chromium(III) potassium sulfate dodecahydrate

ACS reagent, ≥98%

Synonym(s):

Chrome alum, Potassium chromium(III) sulfate dodecahydrate

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About This Item

Linear Formula:
CrK(SO4)2 · 12H2O
CAS Number:
Molecular Weight:
499.40
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

Assay

≥98%
98.0-102.0% (ACS specification)

form

crystals

reaction suitability

reagent type: catalyst
core: chromium

impurities

≤0.01% insolubles

mp

89 °C (lit.)

anion traces

chloride (Cl-): ≤0.002%

cation traces

Al: ≤0.02%
Fe: ≤0.01%
NH4+: ≤0.01%
heavy metals (as Pb): ≤0.01%

SMILES string

O.O.O.O.O.O.O.O.O.O.O.O.[K+].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Cr.K.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;;2*(H2,1,2,3,4);12*1H2/q+3;+1;;;;;;;;;;;;;;/p-4

InChI key

ZFVHBEKVAITXHW-UHFFFAOYSA-J

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General description

Chromium(III) potassium sulfate dodecahydrate (Potassium chromium(III) sulfate dodecahydrate, Chrome alum) is widely used chemical in dyeing and textile industry. It can be synthesized by reacting sulfur dioxide with potassium dichromate (dissolved in sulfuric acid) at -38°C.

Application

Chromium(III) potassium sulfate dodecahydrate [KCr(SO4)2.12H2O] has been used for the dissolution of gelatin in various studies.
It may be used as a starting material in the synthesis of quasi-monodisperse spherical core-shell particles of Cr/α-Cr2O3 to be used as solar absorbers.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


Certificates of Analysis (COA)

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Black Cr/α-Cr2O3 nanoparticles based solar absorbers.
Khamlich S, et al.
Physica B: Condensed Matter, 407(10), 1509-1512 (2012)
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The Journal of cell biology, 204(5), 647-657 (2014-02-26)
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The ultrastructure of endochondral bone was studied using an aqueous solution of chromic potassium sulphate as the decalcifying agent. 0.5 mm thick sections of rat tibiae were fixed in buffered glutaraldehyde, immersed in an aqueous solution of 1% chromic potassium

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