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  • Photophysical properties of three coordinated copper(i) complexes bearing 1,10-phenanthroline and a monodentate phosphine ligand.

Photophysical properties of three coordinated copper(i) complexes bearing 1,10-phenanthroline and a monodentate phosphine ligand.

Dalton transactions (Cambridge, England : 2003) (2017-10-19)
Daichi Kakizoe, Michihiro Nishikawa, Yasuo Fujii, Taro Tsubomura
ZUSAMMENFASSUNG

We report the synthesis and photophysical properties of Cu(i) complexes with 1,10-phenanthroline (phen) and monodentate phosphine ligands. Single crystal X-ray structural analysis revealed that these have three-coordinated trigonal planar geometries. We also found that one of them, [Cu(phen)(Johnphos)]BF

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
1,10-Phenanthrolin, ≥99%
Sigma-Aldrich
Tetrakis(acetonitril)kupfer(I)tetrafluorborat, 97%
Sigma-Aldrich
Tri(o-tolyl)phosphin, 97%
Sigma-Aldrich
(2-Biphenylyl)-di-tert.-butylphosphin, 97%
Sigma-Aldrich
CyJohnPhos, 97%
Sigma-Aldrich
Tris(3,5-dimethylphenyl)phosphin, 96%