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91719

Trifluoressigsäureanhydrid

derivatization grade (GC derivatization), LiChropur, ≥99.0% (GC)

Synonym(e):

TFAA

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Ihnen/SKUVerfügbarkeitPreis
10 mL
Warenkorb auf Verfügbarkeit prüfen
€ 90,20
10 x 1 mL
Warenkorb auf Verfügbarkeit prüfen
€ 210,00
50 mL
Warenkorb auf Verfügbarkeit prüfen
€ 295,00

Über diesen Artikel

Lineare Formel:
(CF3CO)2O
CAS-Nummer:
Molekulargewicht:
210.03
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-982-9
Beilstein/REAXYS Number:
746197
MDL number:
Assay:
≥99.0% (GC)
Grade:
derivatization grade (GC derivatization)
Technique(s):
gas chromatography (GC): suitable (ECD)
Bp:
39.5-40 °C (lit.)
Vapor pressure:
6.28 psi ( 20 °C)

€ 90,20


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grade

derivatization grade (GC derivatization)

Quality Segment

vapor pressure

6.28 psi ( 20 °C)

assay

≥99.0% (GC)

form

liquid

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations, reagent type: derivatization reagent
reaction type: Esterifications

technique(s)

gas chromatography (GC): suitable (ECD)

refractive index

n20/D 1.3 (lit.)

bp

39.5-40 °C (lit.)

mp

−65 °C (lit.)

density

1.511 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

FC(F)(F)C(=O)OC(=O)C(F)(F)F

InChI

1S/C4F6O3/c5-3(6,7)1(11)13-2(12)4(8,9)10

InChI key

QAEDZJGFFMLHHQ-UHFFFAOYSA-N

Application

Weitere Informationen entnehmen Sie den Produktinformationen.
Geeignet für die Derivatisierung von Aminen, Arylaminen, phenolischen Aminen, primären Aminen, tertiären aromatischen Aminen, Aminosäuren, Aminoalkylphosphorsäuren, 2-Aminoethylphosphorsäure, 1-Hydroxy-2-aminoethylphosponsäure, Amphetaminen, Beta-Blockern, Kreatinin, Desipramin, Dopamin, Glutathion, Glycol (MOPEG), guanidinhaltigen Arzneimitteln, Histidin, n-Hydroxy-2-fluorenylacetamid, n-Hydroxylaminen, Hydroxysäuren, p-Hydroxyamphetaminen, 4-Hydroxycoumarinen, p-Hydroxynorephedrin, Hydroxysteroiden, 5-Hydroxytryptamin, Indolen, Jodoaminosäuren, Carbaryl und hydroxylierten Metaboliten, Metanephrin, Methylphenidat, Norepinephrin, Normetanephrin, Peptidamid, Phenformin, Phenolen, Phentermin, der Aminosäure Phenylthiohydantoin, Propranolol, Sulfonamiden, Sulfonylharnstoffen, Thiamin, Vanillinmandelsäure, trisubstituierten Harnsäuren und Harnsäure.

Other Notes

Zum Schutz prim. und sek. Amine, Derivate sind flüchtiger
Reagenz für Carbethoxy-, Butylester-, N-Methyl-, Methylester-, Di(trifluoracetyl)-, Hexafluorisopropylester-, Acetyl- oder Trifluoracetyl-phenylthiohydantoine, Trifluoracetyl-(2-hydroxy-2-methyl)ethyl-, n-Trifluoracetyl, Trifluoracetyl (TFA)-, Trifluoracetamid-, 4-Trifluormethyl-2-, 6-Diamino-1,3,5-triazineacetyl- und Trifluoracetyl-Vanillin.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Dieser Artikel
917078045774564
technique(s)

gas chromatography (GC): suitable (ECD)

technique(s)

HPLC: suitable, LC/MS: suitable

technique(s)

LC/MS: suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

assay

≥99.0% (GC)

assay

≥99.0% (GC)

assay

≥99.0% (GC)

assay

≥99.0% (GC)

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

grade

derivatization grade (GC derivatization)

grade

-

grade

-

grade

analytical standard

form

liquid

form

liquid

form

liquid

form

-

bp

39.5-40 °C (lit.)

bp

72.4 °C (lit.)

bp

72.4 °C (lit.)

bp

72.4 °C (lit.)


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

supp_hazards

Lagerklasse

8B - Non-combustible corrosive hazardous materials

wgk

WGK 2

ppe

Faceshields, Gloves, Goggles



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. 製薬会社で医薬品の品質試験を行なっている者です。この無水トリフルオロ酢酸の物性として、bp(boiling point:沸点?)がありますが、これは日局などの公定書に基づいて試験実施されておりますでしょうか。可能であれば、試験法の詳細をご教示いただきたいです。ご回答お願いいたします。

    1 answer
    1. As listed in the properties section of the product page, the boiling point for this material is 39.5-40 °C. The physical properties are reported from cited in the literature . Neither the testing, nor the processing, is according to the Japanese Pharmacopoeia or other similar agencies. These methods are considered proprietary and may not be shared. The product is intended for research use only.

      Helpful?

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