908800

Chiralyst Rh660

Umicore, powder

• Synonym(e): 1,2-Bis-[(2R,5R)-2,5-diethylphospholano]-benzol-(1,5-cyclooctadien)-rhodium(I)-tetrafluoroborat, (R,R)-Et-DUPHOS-Rh
• Empirische Formel (Hill-System): C₃₀H₄₈BF₄P₂Rh
• CAS-Nummer: 228121-39-9
• Molekulargewicht: 660.36
• UNSPSC Code: 12352005
• NACRES: NA.22

Eigenschaften

• Produktname: Chiralyst Rh660, Umicore
• form: powder
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Noyori Asymmetric Hydrogenation
• SMILES string: C[CH+]C.CC[C@@H]1CC[C@@H](CC)P12C3=C(P4([Rh](C)2C)[C@H](CC)CC[C@H]4CC)C=CC=C3.FB(F)F.C5C/C=C\CC/C=C\5.[F-]
• InChI: 1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1
• InChI key: DSYBEQKPSKLNMC-KYOOHHHUSA-N

Beschreibung

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

• Asymmetric hydrogenation reactions

Chiralyst Rh660 is a homogeneous catalyst useful for asymmetric reactions and asymmetric hydrogenation.
The catalyst works well with privileged ligands.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Preparation Note

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable