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Merck

05-2170

Sigma-Aldrich

Ammoniumcer(IV)-nitrat

JIS special grade, ≥95.0%

Synonym(e):

Cer(IV)-ammoniumnitrat

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About This Item

Lineare Formel:
Ce(NH4)2(NO3)6
CAS-Nummer:
Molekulargewicht:
548.22
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:

Qualität

JIS special grade

Assay

≥95.0%

Form

crystalline

Verfügbarkeit

available only in Japan

SMILES String

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChIKey

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Lagerklassenschlüssel

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Analysenzertifikate (COA)

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Aliasghar Jarrahpour et al.
Molecules (Basel, Switzerland), 12(10), 2364-2379 (2007-11-06)
It is shown that the N-(p-ethoxyphenyl) group on beta-lactams can be oxidatively removed by ceric ammonium nitrate in good yield. Fourteen new N-(p-ethoxyphenyl)-2-azetidinones 8a-n were synthesized through standard [2+2] ketene-imine cycloadditions (Staudinger reaction). Treatment of these compounds with ceric ammonium
Alexander M Jacobine et al.
The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)
The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.
Ahmad Shaabani et al.
Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)
The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation

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