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GF88166627

Iridium

wire, straight, 50mm, diameter 0.7mm, as drawn, 99.9%

Synonym(e):

Iridium

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About This Item

Empirische Formel (Hill-System):
Ir
CAS-Nummer:
7439-88-5
Molekulargewicht:
192.22
MDL-Nummer:
MFCD00011062
UNSPSC-Code:
12352300
PubChem Substanz-ID:
329813270
NACRES:
NA.23

Assay

≥99.9%

Form

wire

Hersteller/Markenname

Goodfellow 881-666-27

Widerstandsfähigkeit

4.71 μΩ-cm

bp

4130 °C (lit.)

mp (Schmelzpunkt)

2450 °C (lit.)

Dichte

22.65 g/cm3 (lit.)

SMILES String

[Ir]

InChI

1S/Ir

InChIKey

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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Stephen J Roseblade et al.
Accounts of chemical research, 40(12), 1402-1411 (2007-08-04)
Asymmetric hydrogenation is one of the most important catalytic methods for the preparation of optically active compounds. For a long time the range of olefins that could be hydrogenated with high enantiomeric excess was limited to substrates bearing a coordinating
Paolo Tosatti et al.
Organic & biomolecular chemistry, 10(16), 3147-3163 (2012-03-13)
Since their discovery in 1997, iridium-catalysed asymmetric allylic substitutions have been developed into a broadly applicable tool for the synthesis of chiral building blocks via C-C and C-heteroatom bond formation. The remarkable generality of these reactions and the high levels
Soo Bong Han et al.
Chemical communications (Cambridge, England), (47)(47), 7278-7287 (2009-12-22)
Existing methods for enantioselective carbonyl allylation, crotylation and tert-prenylation require stoichiometric generation of pre-metallated nucleophiles, and often employ stoichiometric chiral modifiers. Under the conditions of transfer hydrogenation employing an ortho-cyclometallated iridium C,O-benzoate catalyst, enantioselective carbonyl allylations, crotylations and tert-prenylations are
Etienne Baranoff et al.
Chemical Society reviews, 33(3), 147-155 (2004-03-18)
In order to mimic the photosynthetic reaction centre and better understand photoinduced electron transfer processes, a family of compounds has been studied for the past 15 years. These are transition metal complexes, M(tpy)(2) where tpy is a 2,2':6',2" terpyridine based
S Murahashi et al.
Accounts of chemical research, 33(4), 225-233 (2000-04-25)
The discovery of a new chemical reaction often leads to new applications and new chemical principles. Low-valent ruthenium and iridium hydride complexes are highly useful redox Lewis acid and base catalysts. Nitriles are activated by these catalysts and undergo reactions
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