717193

1-(p-Toluolsulfonyl)-pyrrol-2-boronsäure-MIDAester

• Empirische Formel (Hill-System): C₁₆H₁₇BN₂O₆S
• CAS-Nummer: 1311484-50-0
• Molekulargewicht: 376.19
• MDL-Nummer: MFCD15144862
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 329763463

Eigenschaften

• Form: solid
• mp (Schmelzpunkt): 216-220 °C
• SMILES String: CN1CC(=O)OB(OC(=O)C1)c2cccn2S(=O)(=O)c3ccc(C)cc3
• InChI: 1S/C16H17BN2O6S/c1-12-5-7-13(8-6-12)26(22,23)19-9-3-4-14(19)17-24-15(20)10-18(2)11-16(21)25-17/h3-9H,10-11H2,1-2H3
• InChIKey: HLSJWIMKWDEIJR-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Excludes solvent of crystallization. May contain up to 10 wt. % acetone.

Anwendung

MIDA boronate involved in regioselective cross-coupling for synthesis of highly substituted biaryl scaffolds

Reactant for:
Synthesis of atropisomerically defined, highly substituted biaryl scaffolds through catalytic enantioselective bromination and regioselective cross-coupling

MIDA boronates as stable boronic acid surrogates for classically challenging cross-couplings.

Suzuki Cross-Coupling with MIDA Boronates

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: nwg
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable