710504

Bis-(4-methoxyphenyl)-phosphin

• Empirische Formel (Hill-System): C₁₄H₁₅O₂P
• CAS-Nummer: 84127-04-8
• Molekulargewicht: 246.24
• MDL-Nummer: MFCD15143653
• UNSPSC-Code: 12352112
• PubChem Substanz-ID: 329762928
• NACRES: NA.22

Eigenschaften

• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reagent type: ligand
• mp (Schmelzpunkt): 36-40 °C
• Funktionelle Gruppe: phosphine
• SMILES String: COc1ccc(Pc2ccc(OC)cc2)cc1
• InChI: 1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3
• InChIKey: FWKICRREDMVWRF-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Enantioselective Ir-catalyzed hydrogenation
• Palladium-catalyzed asymmetric additions
• Alkali-metal-catalyzed addition reactions
• Preparation of different DIOP-type ligands for uses in Rh-catalyzed asymmetric hydrogenation

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H228,H315,H319,H335
• P-Sätze: P210 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): >230.0 °F - closed cup
• Flammpunkt (°C): > 110 °C - closed cup