675555

1,2-Bis[(2R,5R)-2,5-(Dimethylphospholano]ethan(cyclooctadien)rhodium(I)tetrafluorborat

• Empirische Formel (Hill-System): C₂₂H₄₀BF₄P₂Rh
• CAS-Nummer: 305818-67-1
• Molekulargewicht: 556.21
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24885288

Eigenschaften

• Form: solid
• SMILES String: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2CCP3[C@H](C)CC[C@H]3C
• InChI: 1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m1.../s1
• InChIKey: CVUPEPGZCZHSOF-ZTCBNWEGSA-N

Beschreibung

Anwendung

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

• Preparation of substituted phenylalanine via asymmetric hydrogenation of N-acetyldehydroamino acid precursor
• Enantioselective preparation of trifluoromethyl amino acids via asymmetric hydrogenation
• Asymmetric hydrogenation of acetamidocinnamate

Rechtliche Hinweise

Sold in collaboration with Kanata Chemical Technologies, Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves