598089

Dicarbonyl-cyclopentadienyl-(tetrahydrofuran)-eisen(II)-tetrafluoroborat

• Empirische Formel (Hill-System): C₁₁H₁₃BF₄FeO₃
• CAS-Nummer: 63313-71-3
• Molekulargewicht: 335.87
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 24881737
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: core: iron; reagent type: catalyst
• mp (Schmelzpunkt): 110 °C (dec.) (lit.)
• Lagertemp.: 2-8°C
• SMILES String: [Fe+].[C-]#[O+].[C-]#[O+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.C2CCOC2
• InChI: 1S/C5H5.C4H8O.2CO.BF4.Fe/c2*1-2-4-5-3-1;2*1-2;2-1(3,4)5;/h1-5H;1-4H2;;;;/q;;;;-1;+1
• InChIKey: UEQAYXWNQGYVGN-UHFFFAOYSA-N

Beschreibung

Anwendung

Catalyst for:

• Preparation of β-keto esters via Lewis acid-catalyzed addition of Et diazoacetate to arylaldehydes
• Iron mediated nitrenoid transfer
• Lewis acid catalyzed aziridination, cyclopropanation, and insertion reaction with diazo compounds
• Diels-Alder reaction of dienes with enones

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302 + H312 + H332
• P-Sätze: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable