499021

(2-Naphthylmethyl)zinkbromid -Lösung

0.5 M in THF

• Lineare Formel: C₁₀H₇CH₂ZnBr
• CAS-Nummer: 152329-44-7
• Molekulargewicht: 286.48
• MDL-Nummer: MFCD01311438
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24873248
• NACRES: NA.22

Eigenschaften

• Konzentration: 0.5 M in THF
• Dichte: 0.978 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: Br[Zn]Cc1ccc2ccccc2c1
• InChI: 1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1
• InChIKey: IKDINBHMSAHXCA-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.

Anwendung

(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:

• 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
• (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.

Rechtliche Hinweise

Product of Rieke^® Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H225,H319,H335,H336,H351
• P-Sätze: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup