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452912

Natriumhydrid

greener alternative

60 % dispersion in mineral oil

Synonym(e):

Sodium monohydride

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Ihnen/SKUVerfügbarkeitPreis
5 g
Warenkorb auf Verfügbarkeit prüfen
€ 41,20
100 g
Warenkorb auf Verfügbarkeit prüfen
€ 51,00
500 g
Warenkorb auf Verfügbarkeit prüfen
€ 147,00
1 kg
Warenkorb auf Verfügbarkeit prüfen
€ 223,00
2 kg
Warenkorb auf Verfügbarkeit prüfen
€ 396,00
5 kg
Warenkorb auf Verfügbarkeit prüfen
€ 921,00

Über diesen Artikel

Lineare Formel:
NaH
CAS-Nummer:
Molekulargewicht:
24.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Form:
powder (moist, paste-like)

€ 41,20


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form

powder (moist, paste-like)

Quality Segment

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

60 % dispersion in mineral oil

mp

800 °C (dec.) (lit.)

greener alternative category

SMILES string

[Na]

InChI

1S/Na.H

InChI key

MPMYQQHEHYDOCL-UHFFFAOYSA-N

General description

Wir verpflichten uns, Ihnen umweltfreundlichere Alternativprodukte anzubieten, die ein oder mehrere der „12 Prinzipien der Grünen Chemie“ erfüllen. Dieses Produkt wurde zu Zwecken der Energieeffizienz verbessert. Weitere Einzelheiten dazu finden Sie hier.

Application

Direkte Interkalation in C60 führt zum supraleitenden Material (NaH)4C60.
Natriumhydrid (60 % Dispersion in Mineralöl) (NaH) kann für viele verschiedene Anwendungsbereiche eingesetzt werden wie beispielsweise:
  • Vorbereitung eines Weichmachers zur Bildung eines festen Polymerelektrolyten (SPE) für optoelektronische Anwendungsbereiche
  • Synthese von Heteroaryl-Thioethern, den gebräuchlichen Bestandteilen therapeutischer Verbindungen
  • Vorbereitung von Natriumaluminiumhydrid (NaAlH4), das als Wasserstoffspeichermaterial verwendet werden kann(3)
  • Base und Reduktionsmittel für die Deprotonierung von Alkoholen, Phenolen, Amiden, Ketonen und anderen Funktionsgruppen(4)
  • zur potentiellen Verwendung bei der Speicherung von Wärmeenergie(5)


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Dieser Artikel
2234411.06462655104
reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

-

reaction suitability

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

powder (moist, paste-like)

form

powder

form

pellets

form

powder

mp

800 °C (dec.) (lit.)

mp

800 °C (dec.) (lit.)

mp

318 °C (lit.)

mp

318 °C (lit.)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

concentration

60 % dispersion in mineral oil

concentration

-

concentration

-

concentration

-


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pictograms

FlameCorrosion

signalword

Danger

Lagerklasse

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 1 - Met. Corr. 1 - Skin Corr. 1A - Water-react. 1



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Analysenzertifikate (COA)

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Questions

1–9 of 9 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. please share the CAS No, of the mineral oil incorporated in the product.

    1 answer
    1. The Chemical Abstracts Service (CAS) Registry number for the mineral oil is [8042-47-5]. The CAS number for the sodium hydride is [7646-69-7].

      Helpful?

  4. What is the packaging configuration for Product 452912, Sodium hydride in Mineral Oil?

    1 answer
    1. The 5 gram unit is packaged in an amber glass bottle. The 100 gram and 500 gram quantities are packaged in a paint can. The product is in a bag in the can and the can be opened by removing the plastic seal from the top of the can. An 18 L steel drum is used for packaging the 2 kg and 5 kg size.

      Helpful?

  5. How do you dispose of Product 452912, Sodium hydride in Mineral Oil?

    1 answer
    1. In accordance with our MSDS, we recommend you contact a licensed waste disposal company to dispose of this material.  If you have small  quantities to dispose of, the Hazardous Laboratory Chemicals Disposal Guide : 2nd Edition, recommends you wear eye protection, laboratory coat, and nitrile gloves. In the fume hood , mix the hydride with a 1:1:1 mixture by weight of sodium carbonate or calcium carbonate, clay cat litter (bentonite), and sand. Slowly and cautiously add butanol ( about 38 mL/g of hydride) until the reaction ceases. Then add water very carefully until all of the hydride is destroyed. Let stand until solids settle. Decant liquid into the drain. The solid residue may be discarded with normal refuse.

      Helpful?

  6. What is Product 452912, Sodium hydride in Mineral Oil, soluble in?

    1 answer
    1. According to the chemicals encyclopedia published by the Royal Society of Chemistry:13th Edition this product will react explosively with water and violently with lower alcohols.  It is soluble in molten sodium hydroxide and can spontaneously ignite with moist air.

      Helpful?

  7. When does Product 452912, Sodium hydride in Mineral Oil, decompose?

    1 answer
    1. According to literature, this product starts to decompose with the evolution of hydrogen at about 255 deg C and completely decomposes at 800 deg C ( Condensed Chemical Dictionary, Twelfth Edition ).

      Helpful?

  8. What is the particle size of Product 452912, Sodium hydride in Mineral Oil?

    1 answer
    1. Particle size is not one of our specifications so we have not tested for it and neither has the vendor. According to literature though, the particle size could range from 5 - 50 um (Condensed Chemical Dictionary, Twelfth Edition).

      Helpful?

  9. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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