344109

(−)-(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)-ferrocenyl]-ethylamin

95%

• Empirische Formel (Hill-System): C₂₆H₂₈FeNP
• CAS-Nummer: 55700-44-2
• Molekulargewicht: 441.33
• MDL-Nummer: MFCD00075286
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24861224

Eigenschaften

• Assay: 95%
• Optische Aktivität: [α]20/D −355°, c = 0.6 in ethanol
• Eignung der Reaktion: reaction type: Asymmetric synthesis; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• mp (Schmelzpunkt): 141-143 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)C
• InChI: 1S/C21H23NP.C5H5.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-2-4-5-3-1;/h4-17H,1-3H3;1-5H;/t17-;;/m1../s1
• InChIKey: RCAFPSZHKFOLEE-ZEECNFPPSA-N

Beschreibung

Anwendung

Ligand used in the enantioselective vinylation of aldehydes.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302 + H312 + H332,H315,H319,H335
• P-Sätze: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves