273112

(1R,E)-(+)-Campherchinon-3-oxim

99%

• Synonym(e): (1R,E)-(+)-2,3-Bornandion-3-oxim, anti-(1R)-(+)-Campherchinon-3-oxim
• Empirische Formel (Hill-System): C₁₀H₁₅NO₂
• CAS-Nummer: 31571-14-9
• Molekulargewicht: 181.23
• Beilstein: 3200377
• MDL-Nummer: MFCD00074848
• UNSPSC-Code: 12352115
• PubChem Substanz-ID: 24856531
• NACRES: NA.22

Eigenschaften

• Assay: 99%
• Form: solid
• Optische Aktivität: [α]25/D +200°, c = 1 in ethanol
• mp (Schmelzpunkt): 153-156 °C (lit.)
• Funktionelle Gruppe: ketone; oxime
• SMILES String: [H][C@@]12CC[C@@](C)(C(=O)\C1=N/O)C2(C)C
• InChI: 1S/C10H15NO2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11-13/h6,13H,4-5H2,1-3H3/b11-7-/t6-,10+/m1/s1
• InChIKey: YRNPDSREMSMKIY-HAKKTOSXSA-N

Beschreibung

Anwendung

(1R,E)-(+)-Camphorquinone 3-oxime can be used to prepare chiral camphor-oxazoline auxiliary, which is used to blend diastereoselectivity and isomer separability for the efficient synthesis of bicuculline, egenine, corlumine, and corytensine.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves