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1.06516

Sodium thiosulfate pentahydrate

for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Synonym(s):

Sodium thiosulfate pentahydrate, Antichlor

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About This Item

Empirical Formula (Hill Notation):
Na2O3S2 · 5H2O
CAS Number:
Molecular Weight:
248.18
UNSPSC Code:
12352302
EC Index Number:
231-867-5
NACRES:
NA.21
MDL number:
Assay:
99.5-101.0% (iodometric)
Grade:
ACS reagent
Form:
solid
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grade

ACS reagent

Quality Segment

agency

reag. ISO, reag. Ph. Eur., suitable for SM 2310, suitable for SM 2320, suitable for SM 4500 - NH3

product line

EMSURE®

assay

99.5-101.0% (iodometric)

form

solid

potency

>5000 mg/kg LD50, oral (Rat)

impurities

≤0.005% Insoluble matter

pH

6.0-7.5 (20 °C, 100 g/L in H2O)

mp

48 °C

density

1.74 g/cm3 at 20 °C

bulk density

1000 kg/m3

anion traces

chloride (Cl-): ≤0.008%, sulfate, sulfite (as SO42-): ≤0.1%, sulfide (S2-): passes test

cation traces

Ca: ≤0.002%, Cu: ≤0.0005%, Fe: ≤0.0005%, K: ≤0.001%, Mg: ≤0.001%, N: ≤0.002%, Pb: ≤0.0005%, heavy metals (as Pb): ≤0.001%

storage temp.

2-30°C

SMILES string

[Na+].[Na+].[S](=S)(=O)([O-])[O-].O.O.O.O.O

InChI

1S/2Na.H2O3S2.5H2O/c;;1-5(2,3)4;;;;;/h;;(H2,1,2,3,4);5*1H2/q2*+1;;;;;;/p-2

InChI key

PODWXQQNRWNDGD-UHFFFAOYSA-L

Application


  • Synthesis of Aryl Amides from Acyl-Bunte Salts and Aryl Azides: Details the application of sodium thiosulfate pentahydrate in synthetic organic chemistry, specifically in the synthesis of aryl amides, illustrating its utility in facilitating complex chemical reactions (Chen et al., 2023).

Analysis Note

Assay (iodometric): 99.5 - 101.0 %
Identity: passes test
Appearance of solution: passes test
Insoluble matter: ≤ 0.005 %
pH-value (5 %; water, 25 °C): 6.0 - 7.5
pH-value (10 %; water): 6.0 - 7.5
Chloride (Cl): ≤ 0.008 %
Sulfate and sulphite (as SO₄): ≤ 0.1 %
Sulfide (S): passes test
Heavy metals (as Pb): ≤ 0.001 %
Total nitrogen (N): ≤ 0.002 %
Ca (Calcium): ≤ 0.002 %
Cu (Copper): ≤ 0.0005 %
Fe (Iron): ≤ 0.0005 %
K (Potassium): ≤ 0.001 %
Mg (Magnesium): ≤ 0.001 %
Pb (Lead): ≤ 0.0005 %
Corresponds to ACS, ISO, Reag. Ph Eur

Other Notes

Replaces: SX0815-1; SX0815

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
134791.06514217247
form

solid

form

crystalline

form

crystalline, solid

form

crystalline powder, crystals, pellets

assay

99.5-101.0% (iodometric)

assay

99.0-100.5% (USP, dry basis), 99.0-101.0% (EP)

assay

-

assay

≥99.5%

Quality Level

300

Quality Level

200

Quality Level

500

Quality Level

200

grade

ACS reagent

grade

-

grade

-

grade

ACS reagent

mp

48 °C

mp

-

mp

48 °C

mp

-

pH

6.0-7.5 (20 °C, 100 g/L in H2O)

pH

6.0-8.4 (20 °C, 10%)

pH

6.0-7.5 (20 °C, 100 g/L in H2O)

pH

6.0-8.4 (25 °C, 5%)


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Storage Class

13 - Non Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



Certificates of Analysis (COA)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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