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241725

Sigma-Aldrich

Triisopropylsilyl chloride

97%

Synonym(s):

Chlorotriisopropylsilane, TIPSCl, Triisopropylchlorosilane, Triisopropylsilyl chloride

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About This Item

Linear Formula:
[(CH3)2CH]3SiCl
CAS Number:
13154-24-0
Molecular Weight:
192.80
Beilstein:
1737446
MDL number:
MFCD00009656
UNSPSC Code:
12352103
PubChem Substance ID:
24854324
NACRES:
NA.22

vapor pressure

1.16 mmHg ( 20 °C)

Assay

97%

form

liquid

refractive index

n20/D 1.452 (lit.)

bp

198 °C/739 mmHg (lit.)

density

0.901 g/mL at 25 °C (lit.)

SMILES string

CC(C)[Si](Cl)(C(C)C)C(C)C

InChI

1S/C9H21ClSi/c1-7(2)11(10,8(3)4)9(5)6/h7-9H,1-6H3

InChI key

KQIADDMXRMTWHZ-UHFFFAOYSA-N

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Related Categories

Application

Use of TIPS substituted alkynes in a preparation of silyl vinyl ketenes from chromium carbene complexes.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

147.2 °F - closed cup

Flash Point(C)

64 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis (1991)
William H Moser et al.
The Journal of organic chemistry, 71(17), 6542-6546 (2006-08-12)
Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] annulation reactions was investigated. The best results

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