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Merck
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Documentos

442250

Supelco

1,4-Dinitrobenzene

analytical standard

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About This Item

Fórmula lineal:
C6H4(NO2)2
Número de CAS:
100-25-4
Peso molecular:
168.11
Beilstein/REAXYS Number:
1105828
EC Number:
202-833-7
MDL number:
MFCD00007314
UNSPSC Code:
12000000
PubChem Substance ID:
24867756

grade

analytical standard

packaging

ampule of 1000 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

183.4 °C/34 mmHg (lit.)

mp

170-173 °C (lit.)

density

1.625 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

room temp

SMILES string

[O-][N+](=O)c1ccc(cc1)[N+]([O-])=O

InChI

1S/C6H4N2O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4H

InChI key

FYFDQJRXFWGIBS-UHFFFAOYSA-N

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

302.0 °F - closed cup

flash_point_c

150 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
LC20788V
LC15945V
LC14111V
LC12922V
LC04576V

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Silvia M Barolo et al.
The Journal of organic chemistry, 71(22), 8493-8499 (2006-10-27)
The photostimulated intramolecular ortho-arylation reactions of bromoarenes linked with pendant phenoxy containing N-substituted tetrahydroisoquinolines in liquid ammonia afforded aporphine (54-82% yield) alkaloid derivatives via SRN1 reactions. This strategy was extended for the first time to the synthesis of a homoaporphine
N Kessler et al.
Proteins, 34(3), 383-394 (1999-02-19)
The sequences of the variable regions of three monoclonal antibodies with different specificities to cholesterol monohydrate and 1,4-dinitrobenzene crystals were determined. The structures of their binding sites were then modeled, based on homology to other antibodies of known structure. Two
Akio Kamimura et al.
Molecules (Basel, Switzerland), 17(5), 4782-4790 (2012-04-27)
S(RN)1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with
Methemoglobinemia due to occupational exposure to dinitrobenzene--Ohio, 1986.
MMWR. Morbidity and mortality weekly report, 37(22), 353-355 (1988-06-10)
N Kessler et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 10(12), 1435-1442 (1996-10-01)
Monoclonal antibodies have been elicited and selected after injection of crystals of 1,4-dinitrobenzene (1,4-DNB) and cholesterol monohydrate in mice. The reactivity of some of these antibodies to 1,4-DNB crystals, cholesterol monohydrate crystals, and other solid substrates has been characterized. Two
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