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Merck

90781

Sigma-Aldrich

Tributylamine

puriss. plus, ≥99.5% (GC)

Sinónimos:

Tri-n-butylamine

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10 ML
US$ 53,80
50 ML
US$ 155,00

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10 ML
US$ 53,80
50 ML
US$ 155,00

About This Item

Fórmula lineal:
[CH3(CH2)3]3N
Número de CAS:
Peso molecular:
185.35
Beilstein:
1698872
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.21
bp:
216 °C (lit.)

US$ 53,80

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densidad de vapor

6.38 (vs air)

Nivel de calidad

presión de vapor

0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

grado

puriss. plus

Ensayo

≥99.5% (GC)

Formulario

liquid

temp. de autoignición

410 °F

lim. expl.

6 %

técnicas

GC/GC: suitable

impurezas

≤0.2% water

índice de refracción

n20/D 1.428 (lit.)
n20/D 1.429

bp

216 °C (lit.)

mp

−70 °C (lit.)

densidad

0.778 g/mL at 25 °C (lit.)

grupo funcional

amine

cadena SMILES

CCCCN(CCCC)CCCC

InChI

1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

Clave InChI

IMFACGCPASFAPR-UHFFFAOYSA-N

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Descripción general

Tributylamine is a tertiary amine. It has been reported to prevent the corrosion of mild steel in HCl solution.[1]

Aplicación

Tributylamine (n-Bu3N) may be used in the following studies:
  • To compose the mobile phase for the liquid chromatography tandem mass spectrometry (LC-MS/MS) analysis.[2]
  • Preparation of PdCl,N and PdOAc,N (palladium nanoparticles).[3]
  • As an additive during the synthesis of 3-bromothieno[3,2-c]pyridine-4-(5H)-one.[4]

Pictogramas

Skull and crossbones

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

145.4 °F - closed cup

Punto de inflamabilidad (°C)

63 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins.
Le Bras J, et al.
New. J. Chem., 28(12), 1550-1553 (2004)
Thermal Synthesis of 3-Bromothieno [3, 2-c] pyridin-4-(5H)-one: A Telescoped Procedure with Tributylamine.
Boros EE and Kaldor I.
Journal of Heterocyclic Chemistry, 52(1), 302-305 (2015)
Tributylamine as corrosion inhibitor for mild steel in hydrochloric acid.
Bastidas JM, et al.
J. Mater. Sci., 35(11), 2637-2642 (2000)
Alexander S Misharin et al.
Analytical chemistry, 77(2), 459-470 (2005-01-15)
The analytical performance of an atmospheric pressure sampling, multiple-channel, high-throughput mass spectrometer was investigated using samples of a variety of types. The instrument, based on an array of cylindrical ion traps, was built with four independent channels and here is
I E Flesch et al.
Infection and immunity, 56(6), 1464-1469 (1988-06-01)
Bone marrow-derived murine macrophages are able to inhibit the growth of Mycobacterium bovis and of some strains of M. tuberculosis after stimulation with either recombinant gamma interferon (rIFN-gamma) or lymphokines from antigen-specific T-cell clones. To elucidate the mechanism(s) involved in

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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