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Merck

32951

Supelco

TDCPP

PESTANAL®, analytical standard

Sinónimos:

Phosphorsäure-tris-(1,3-dichlor-2-propylester)

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About This Item

Fórmula empírica (notación de Hill):
C9H15Cl6O4P
Número de CAS:
Peso molecular:
430.90
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

density

1.514 g/mL at 20 °C (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl

InChI

1S/C9H15Cl6O4P/c10-1-7(2-11)17-20(16,18-8(3-12)4-13)19-9(5-14)6-15/h7-9H,1-6H2

InChI key

ASLWPAWFJZFCKF-UHFFFAOYSA-N

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Categorías relacionadas

General description

TDCPP is classified under the chlorinated trialkyl organophosphate flame retardant (OPFR) group of compounds primarily utilized as additives in commercial products such as plastics, paints, textiles, furniture, etc.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TDCPP may be used as an analytical reference standard for the determination of the analyte in:
  • Eggs by liquid chromatography-tandem quadrupole mass spectrometry (LC-MS/MS).
  • Fish samples by gas chromatography-nitrogen-phosphorus detector (GC-NPD), LC-MS/MS and on-line turbulent flow chromatography (TFC) in conjunction with LC-MS/MS.
  • Environmental samples by GC-MS/MS.
  • Fruits and vegetables by GC-MS/MS and GC coupled with electron capture detection.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Chronic 1 - Carc. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

482.0 - 485.6 °F - open cup

flash_point_c

250 - 252 °C - open cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Journal of Chromatography A, 1400(19), 149-155 (2015)
Heather M Stapleton et al.
Environmental science & technology, 46(24), 13432-13439 (2012-11-29)
California's furniture flammability standard Technical Bulletin 117 (TB 117) is believed to be a major driver of chemical flame retardant (FR) use in residential furniture in the United States. With the phase-out of the polybrominated diphenyl ether (PBDE) FR mixture
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Environmental health perspectives, 120(11), 1585-1591 (2012-09-29)
Chlorinated phosphate esters (CPEs) are widely used as additive flame retardants for low-density polyurethane foams and have frequently been detected at elevated concentrations within indoor environmental media. To begin characterizing the potential toxicity of CPEs on early vertebrate development, we
Determination of non-halogenated, chlorinated and brominated organophosphate flame retardants in herring gull eggs based on liquid chromatography-tandem quadrupole mass spectrometry.
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Journal of Chromatography A, 1220(7), 169-174 (2012)
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Environmental health perspectives, 121(5), 580-585 (2013-03-07)
A reduction in the use of polybrominated diphenyl ethers (PBDEs) because of human health concerns may result in an increased use of and human exposure to organophosphate flame retardants (OPFRs). Human exposure and health studies of OPFRs are lacking. We

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