Saltar al contenido
Merck

D198501

Sigma-Aldrich

2,4-Dinitrophenol

moistened with water, ≥98.0%

Sinónimos:

α-Dinitrophenol, 2,4-DNP, DNP

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización


About This Item

Fórmula lineal:
(O2N)2C6H3OH
Número de CAS:
Peso molecular:
184.11
Beilstein/REAXYS Number:
1246142
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

vapor density

6.35 (vs air)

Quality Level

assay

≥98.0%

contains

≥15% water

mp

108-112 °C (lit.)

SMILES string

Oc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H4N2O5/c9-6-2-1-4(7(10)11)3-5(6)8(12)13/h1-3,9H

InChI key

UFBJCMHMOXMLKC-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Application

2,4-Dinitrophenol (DNP) can be used:
  • As a reactant for catalytic reduction reactions.[1][2]
  • To activate carboxylic acids by converting them into dinitrophenyl (DNP) esters.[3]
  • To prepare the corresponding ester via acylation reaction using isobutyric anhydride catalyzed by hafnium triflate.[4]
  • As an effective cocatalyst to accelerate the activity and enantioselectivity of primary amine organocatalyst derived from natural primary amino acids for direct asymmetric aldol reaction.[5]
  • As an alternative activator to tetrazoles in the reaction of phosphoroamidites with nucleosides.[6]

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Desen. Expl. 4 - STOT RE 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Elija entre una de las versiones más recientes:

Certificados de análisis (COA)

Lot/Batch Number

¿No ve la versión correcta?

Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Hafnium inspired activation of highly hindered anhydrides in the acylation of alcohols and polyols.
Mensah E, et al.
Tetrahedron Letters, 59(12), 1094-1098 (2018)
2, 4-Dinitrophenol: a novel activating reagent in nucleotide synthesis via the phosphoramidite route. Design of new effective phosphitylating reagents.
Dabkowski W, et al.
Tetrahedron Letters, 41(39), 7535-7539 (2000)
Photo-Enhanced Selective Reduction of Nitroarenes Over Pt/ZnO Catalyst.
Van T D, et al.
Catalysis Letters, 147(9), 2440-2447 (2017)
Synthesis and stereochemical assignment of geraniol-and nerol-derived Cygerol enantiomers.
Sukhanova A A, et al.
Tetrahedron Asymmetry, 28(12), 1834-1841 (2017)
Chemical-hydrothermal synthesis of oval-shaped graphene/ZnO quantum hybrids and their photocatalytic performances.
Van T D, et al.
Catalysis Communications, 101, 102-106 (2017)

Artículos

Cellular oxidative stress is countered by enzymatic scavengers and antioxidant modulators against reactive oxygen species damage.

Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. How to dissolve D198501?

    1 answer
    1. 2,4-DNP (2,4-dinitrophenylhydrazine) is sparingly soluble in water. To prepare a 0.1M solution of 2,4-DNP (e.g., 500 ml), follow the steps below:
      1. Weigh 9.2 grams of 2,4-DNP and add it to 500 ml of distilled water.
      2. Place the solution on a magnetic stirrer and begin stirring. Note that 2,4-DNP is insoluble in water.
      3. Carefully add solid Tris Base to the solution while stirring until completely dissolved. Typically, 6-8 grams of Tris is sufficient for dissolution.
      4. This process will result in a clear, yellow solution. If necessary, the solution can be filtered.

      Helpful?

  4. Is there any recommended shelf-life or re-test date/period for DNP (D198501)?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one-year warranty from the date of shipment.

      For more information, you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

      Helpful?

Reviews

No rating value

Active Filters

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico