712892

(S)-(−)-2-(Dibenzylamino)propionaldehyde

97%

• Sinónimos: (S)-2-(Dibenzylamino)propanal, N,N-Dibenzyl-L-alaninal
• Fórmula empírica (notación de Hill): C₁₇H₁₉NO
• Número de CAS: 111060-63-0
• Peso molecular: 253.34
• Beilstein/REAXYS Number: 4293933
• MDL number: MFCD11053600
• UNSPSC Code: 12352114
• PubChem Substance ID: 329763158
• NACRES: NA.22

Propiedades

• assay: 96.5-103.5% (NT); 97%
• form: crystals
• optical activity: [α]/D -36.0±2.0°, c = 1 in ethanol
• functional group: aldehyde; amine; phenyl
• storage temp.: 2-8°C
• SMILES string: C[C@@H](C=O)N(Cc1ccccc1)Cc2ccccc2
• InChI: 1S/C17H19NO/c1-15(14-19)18(12-16-8-4-2-5-9-16)13-17-10-6-3-7-11-17/h2-11,14-15H,12-13H2,1H3/t15-/m0/s1
• InChI key: GFYXFRCVQSKSDO-HNNXBMFYSA-N

Descripción

Application

(S)-(-)-2-(Dibenzylamino)propionaldehyde can be employed as a building block for the preparation of:

• Linezolid dipeptide derivatives and 3-oxazolidin-2-one analogs.
• (2R,3S)-3-Dibenzylamine-1-nitrobutan-2-ol by reacting with bromonitromethane via nitro-aldol reaction using SmI₂ as a catalyst.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H317
• pcodes: P261 - P264 - P272 - P280 - P301 + P312 - P302 + P352
• Hazard Classifications: Acute Tox. 4 Oral - Skin Sens. 1
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Faceshields, Gloves