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Merck

669008

Sigma-Aldrich

Tetrakis(dimethylamido)titanium(IV)

packaged for use in deposition systems

Sinónimos:

TDMAT, Tetrakis(dimethylamino)titanium(IV)

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25 G
US$ 2.200,00

US$ 2.200,00

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25 G
US$ 2.200,00

About This Item

Fórmula lineal:
[(CH3)2N]4Ti
Número de CAS:
Peso molecular:
224.17
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23

US$ 2.200,00

PRECIOS SIN IMPUESTOS NACIONALES

Check Cart for Availability

Solicitar un pedido a granel

Nivel de calidad

Ensayo

99.999% (trace metals analysis)

Formulario

liquid

idoneidad de la reacción

core: titanium

bp

50 °C/0.5 mmHg (lit.)

densidad

0.947 g/mL at 25 °C (lit.)

cadena SMILES

CN(C)[Ti](N(C)C)(N(C)C)N(C)C

InChI

1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4

Clave InChI

MNWRORMXBIWXCI-UHFFFAOYSA-N

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Descripción general

Atomic number of base material: 22 Titanium

Aplicación

The product is a precursor for the deposition of titanium dioxide thin films by atomic layer deposition with water.[1] Tetrakis(dimethylamido)titanium(IV) (TDMAT) undergoes exothermal reaction with excess cyclopentadiene to yield tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV).[2]

Pictogramas

FlameCorrosion

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

Riesgos supl.

Código de clase de almacenamiento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

-22.0 °F - closed cup

Punto de inflamabilidad (°C)

-30 °C - closed cup

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Visite la Librería de documentos

Journal of Applied Physics, 102, 083521/1-083521/1 (2007)
Mikami K, et al. et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 2, 494-494 (2014)
Matthew T McDowell et al.
ACS applied materials & interfaces, 7(28), 15189-15199 (2015-06-18)
Light absorbers with moderate band gaps (1-2 eV) are required for high-efficiency solar fuels devices, but most semiconducting photoanodes undergo photocorrosion or passivation in aqueous solution. Amorphous TiO2 deposited by atomic-layer deposition (ALD) onto various n-type semiconductors (Si, GaAs, GaP

Artículos

Atomic Layer Deposition (ALD) technology ensures uniform coating on complex 3D surfaces with precise chemisorption cycles.

Nanocomposite Coatings with Tunable Properties Prepared by Atomic Layer Deposition

Continuous efficiency improvements in photovoltaic devices result from material advancements and manufacturing innovation.

Thin film photovoltaic devices have become increasingly important in efficiently harnessing solar energy to meet consumer demand.

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Questions

1–3 of 3 Questions  
  1. What is the packaged mention in item 669008? Is it the 50ml stainless stell cylinder with valve use with Cambridge Nanotech ALD?

    1 answer
    1. This product is packaged in a steel cylinder and suitable for use in deposition systems only. This cylinder features a diaphragm valve and 1/4" Swagelok® VCR® cap and nickel gasket. Alternatively, product 469858 is packaged in clear glass sealed ampules for ease of access. Please see the link below to review this product option:
      https://www.sigmaaldrich.com/product/aldrich/469858

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  2. I need some details about the packaging: Is it a stainless steel tube with 1/4" VCR fitting connection (Edestahlbehälter mit ¼“ VCR Fitting Anschluss)?

    1 answer
    1. Product 669008 is Tetrakis(dimethylamido)titanium(IV). This is a neat liquid, sold by weight. There is just one listed package size, 25 grams (669008-25G). Based on a density of 0.947 g/mL, the volume of the liquid is 26.4 mL. The product is described as being "packaged for use in a deposition system". It is packaged in a steel cylinder connected to a 316 stainless steel ball-valve, which in turn has a 1/4 inch male Swagelok-brand VCR connection. For a photo of the cylinder, go to the product detail page: https://www.sigmaaldrich.com/product/aldrich/669008
      Click on the link for All Photos; the cylinder is in the second photo.

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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