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379840

Sigma-Aldrich

Platinum(IV) chloride

≥99.99% trace metals basis

Sinónimos:

Platinum tetrachloride

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About This Item

Fórmula lineal:
PtCl4
Número de CAS:
13454-96-1
Peso molecular:
336.89
EC Number:
236-645-1
MDL number:
MFCD00011182
UNSPSC Code:
12352302
PubChem Substance ID:
24863693
NACRES:
NA.23

assay

≥99.99% trace metals basis

form

powder and chunks

reaction suitability

reagent type: catalyst
core: platinum

impurities

≤100.0 ppm Trace Metal Analysis

mp

370 °C (dec.) (lit.)

density

4.303 g/mL at 25 °C (lit.)

SMILES string

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

InChI key

FBEIPJNQGITEBL-UHFFFAOYSA-J

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General description

Platinum (IV)chloride is a highly oxidizing crystalline compound that can easily undergo reduction-oxidation reactions. It is widely used to synthesize Pt-based nanomaterials and catalysts.

Application

Platinum (IV) chloride can be used:
  • As a precursor to synthesize Pt nanoparticles for photocatalytic hydrogen generation.
  • As a starting material to prepare Pt/Al2O3 and Pt/ZrO2-SiO2 catalysts.
  • To fabricate an electrocatalyst for proton exchange fuel cells.
  • As a catalyst for the cyclization of arene−alkynesubstrates via intramolecular electrophilic hydroarylation.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Hybrid metal-Cu2S nanostructures as efficient co-catalysts for photocatalytic hydrogen generation
Jeong-Hyun Park, et al.
Chemical Communications (Cambridge, England), 53, 3277-3280 (2017)
PtIV-Catalyzed Cyclization of Arene?Alkyne Substrates via Intramolecular Electrophilic Hydroarylation
Stefan J. Pastine, et al.},
Organic Letters, 5, 1055-1058 (2003)
Syngas production by carbon dioxide reforming of methane over Pt/Al2O3 and Pt/ZrO2-SiO2 catalysts
Ashvin L. Karemore, et al.
Chemical Engineering Science, 249, 117347-117347 (2022)
Third-body effects of native surfactants on Pt nanoparticle electrocatalysts in proton exchange fuel cells
Young-Hoon Chung, et al.
Chemical Communications (Cambridge, England), 51, 2968-2971 (2015)
Lu Zhao et al.
Zhejiang da xue xue bao. Yi xue ban = Journal of Zhejiang University. Medical sciences, 38(1), 59-66 (2009-03-03)
To construct a drug carrier and gene vector PEG-PEI-Pt. Polyethyleneglycol (PEG) was coupled to polyethylenimine (PEI 600) and platinum tetrachloride; PEG-PEI-Pt complex was formed in ethanol. The complex was characterized by XRD, UV-VIS and FT-IR and the DNA condensation was
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