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205567

Sigma-Aldrich

Zinc fluoride

powder, 99%

Synonym(s):

Zinc difluoride

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About This Item

Linear Formula:
ZnF2
CAS Number:
7783-49-5
Molecular Weight:
103.39
EC Number:
232-001-9
MDL number:
MFCD00011298
UNSPSC Code:
12352300
PubChem Substance ID:
329752015

vapor pressure

1 mmHg ( 970 °C)

Assay

99%

form

powder

reaction suitability

reagent type: catalyst
core: zinc

mp

872 °C (lit.)

density

4.95 g/mL at 25 °C (lit.)

SMILES string

F[Zn]F

InChI

1S/2FH.Zn/h2*1H;/q;;+2/p-2

InChI key

BHHYHSUAOQUXJK-UHFFFAOYSA-L

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General description

Zinc fluoride is a Lewis acid catalyst that can be used in a variety of reactions including esterification, Mukaiyama aldol reaction, Mannich reaction, Friedel-Crafts alkylation, and allylation. It can also be used as an additive in numerous catalytic transformations.

Application

Zinc fluoride can be used as a catalyst to synthesize optically active β-amino ketones and esters via asymmetric Mannich reaction.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H332,H315,H411

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Zinc Fluoride
Turcotte-Savard M, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis.
Guo Y, et al.
Journal of Materials Chemistry, 22(29), 14587-14593 (2009)
Theoretical studies of valence orbital binding energies in solid zinc sulfide, zinc oxide, and zinc fluoride.
Tossell JA.
Inorganic Chemistry, 16(11), 2944-2949 (1977)
J V Embleton et al.
Applied and environmental microbiology, 64(9), 3503-3506 (1998-09-03)
This study evaluated the susceptibility to amine fluorides (AmFs) of planktonic and biofilm cultures of Streptococcus sanguis grown with and without sucrose. Cultures were incubated with AmFs (250 mg of fluoride liter-1) for 1 min. The susceptibility of biofilms was
Hongkun Wu et al.
Hua xi yi ke da xue xue bao = Journal of West China University of Medical Sciences = Huaxi yike daxue xuebao, 33(1), 75-76 (2003-02-26)
To compare the influence of 6 trace element agents containing fluoride versus 6 trace element agents not containing fluoride on the growth of mutants of S. mutans and detect the interaction between fluoride and trace elements. Six trace element agents
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