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Key Documents

749192

Sigma-Aldrich

Poly(styrene-block-methyl methacrylate)

average Mn 104,000, block ratio of 1:1

Synonym(s):

PS-block-PMMA, PS-PMMA

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About This Item

CAS Number:
UNSPSC Code:
12162002

form

solid

mol wt

average Mn 104,000
average Mn 52,000 (PMMA)
average Mn 52,000 (polystyrene)

transition temp

Tm 345-350 °C

Mw/Mn

<1.2

InChI

1S/C8H8.C5H8O2/c1-2-8-6-4-3-5-7-8;1-4(2)5(6)7-3/h2-7H,1H2;1H2,2-3H3

InChI key

ADFPJHOAARPYLP-UHFFFAOYSA-N

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General description

57 kDa PS; 25 kDa PMMA; m ~494; n ~520
PS Mn = 57 ± 6 kg/mol
PMMA Mn = 25 ± 3 kg/mol
PDI of the overall block copolymer <1.2
PS molecular weight verified by SEC (taking an aliquot from the reaction mixture) and the PMMA molecular weight by NMR spectroscopy. The overall block copolymer molecular weight distribution would be determined by SEC.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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S M Belkoff et al.
Bone, 25(2 Suppl), 23S-26S (1999-08-24)
The purpose of this study was to determine the strength and stiffness of osteoporotic vertebral bodies (VBs) subjected to compression fractures and subsequently treated with bipedicular injections of various polymethylmethacrylate cements. Ten spines were harvested from nonembalmed female cadavers (age
Takeshi Ueki et al.
The journal of physical chemistry. B, 111(18), 4750-4754 (2007-02-27)
The solubility and phase behavior of poly(benzyl methacrylate) (PBzMA) and poly(styrene-co-methyl methacrylate) (P(St-co-MMA)) in a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfone)imide ([C(2)mim][NTf(2)]), have been explored as a function of temperature. Although both polymers have solvatophobic phenyl groups and solvatophilic methacrylate
Polymethylmethacrylate: from polymer to dialyzer.
H Sugaya et al.
Contributions to nephrology, 125, 1-8 (1999-01-23)
M E Forsythe et al.
Journal of orthopaedic surgery (Hong Kong), 14(1), 38-42 (2006-04-07)
To compare the pharmacokinetic profile of tobramycin in blood, urine, and at the operative site following the use of Simplex-tobramycin bone cement in primary total hip replacement between patients with and without renal dysfunction. Six patients with renal dysfunction underwent
MN: Surgical LPN files product liability suit: cement Mfgr.'s failure to warn of health hazard.
Nursing law's Regan report, 42(8), 3-3 (2004-08-11)

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