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Key Documents

247022

Sigma-Aldrich

Boron trichloride methyl sulfide complex solution

2.0 M in methylene chloride

Synonym(s):

Dimethyl sulfide-trichloroborane, Trichloroborane-methyl sulfide

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About This Item

Linear Formula:
(CH3)2S·BCl3
CAS Number:
Molecular Weight:
179.30
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst

concentration

2.0 M in methylene chloride

density

1.344 g/mL at 25 °C

SMILES string

C[S+](C)[B-](Cl)(Cl)Cl

InChI

1S/C2H6BCl3S/c1-7(2)3(4,5)6/h1-2H3

InChI key

YNDYUDLLOGOQNW-UHFFFAOYSA-N

Application

Convenient reagent for dealkylation of aryl ethers.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Tetrahedron Letters, 21, 3731-3731 (1980)

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