23070
(1-Chloroethyl)trimethylsilane
technical, ≥90% (GC)
Sign Into View Organizational & Contract Pricing
All Photos(1)
About This Item
Empirical Formula (Hill Notation):
C5H13ClSi
CAS Number:
Molecular Weight:
136.70
Beilstein:
1732094
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical
Assay
≥90% (GC)
form
liquid
refractive index
n20/D 1.422
bp
116 °C (lit.)
density
0.864 g/mL at 20 °C (lit.)
SMILES string
CC(Cl)[Si](C)(C)C
InChI
1S/C5H13ClSi/c1-5(6)7(2,3)4/h5H,1-4H3
InChI key
UWJVDEZZIPJQRF-UHFFFAOYSA-N
Other Notes
Treating this chlorosilane with sec-BuLi gives 1-chloro-1-trimethylsilylethyl lithium which reacts with aldehydes and ketones to form methyl ketones via an intermediate α,β-epoxysilane.; Used in an efficient synthesis of R(+)-frontalin; The Grignard reagent is useful for many reactions
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
68.0 °F
Flash Point(C)
20 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
P. Magnus et al.
Journal of the Chemical Society. Chemical Communications, 297-297 (1978)
F. Cooke et al.
Organometallics, 1, 893-893 (1982)
J.A. Soderquist et al.
The Journal of Organic Chemistry, 45, 3571-3571 (1980)
S. Sato et al.
Journal of Organometallic Chemistry, 344, 71-71 (1988)
T. Hayashi et al.
The Journal of Organic Chemistry, 51, 3772-3772 (1986)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service