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T32409

Sigma-Aldrich

2-Thiophenecarboxaldehyde

98%

Synonym(s):

Thenaldehyde

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About This Item

Empirical Formula (Hill Notation):
C5H4OS
CAS Number:
98-03-3
Molecular Weight:
112.15
Beilstein:
105819
EC Number:
202-629-8
MDL number:
MFCD00005429
UNSPSC Code:
12352100
PubChem Substance ID:
24900117
NACRES:
NA.22

Quality Level

200

Assay

98%

refractive index

n20/D 1.591 (lit.)

bp

198 °C (lit.)
75-77 °C/11 mmHg (lit.)

density

1.2 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[H]C(=O)c1cccs1

InChI

1S/C5H4OS/c6-4-5-2-1-3-7-5/h1-4H

InChI key

CNUDBTRUORMMPA-UHFFFAOYSA-N

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Related Categories

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

170.6 °F - closed cup

Flash Point(C)

77 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000294404
0000222985
0000222978
STBL3208
0000196682

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A tandem IBX-promoted oxidation of primary alcohol to aldehyde and opening of intermediate β,γ-diolcarbonate aldehyde to (E)-γ-hydroxy-α,β-enal has been developed. Remarkably, the carbonate opening delivered exclusively (E)-olefin and no over-oxidation of γ-hydroxy was observed. The method developed has been extended
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International journal of biological macromolecules, 127, 232-239 (2019-01-15)
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