805009

CX200

Umicore

• Synonym(s): (Pd tBu-Ind Cl)₂, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η³-1-tert-Butylindenyl)(μ-Cl)Pd]₂
• Empirical Formula (Hill Notation): C₂₆H₃₀Cl₂Pd₂
• CAS Number: 1779569-01-5
• Molecular Weight: 626.26
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• form: powder
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 166 °C
• SMILES string: CC(C)(C)[C@H]1[C@H]2[C@H](CCCC2)CC1.C[Pd]Cl.C[Pd]Cl.CC(C)(C)c3ccc4c3cccC4

Description

Application

The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.

Legal Information

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Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable