669083
2,2,2-Trifluoroethyl formate
95%
Synonym(s):
TFEF
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About This Item
Linear Formula:
CF3CH2OC(O)H
CAS Number:
Molecular Weight:
128.05
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
95%
refractive index
n20/D <1.001
density
1.317 g/mL at 25 °C
functional group
fluoro
SMILES string
[H]C(=O)OCC(F)(F)F
InChI
1S/C3H3F3O2/c4-3(5,6)1-8-2-7/h2H,1H2
InChI key
CAFROQYMUICGNO-UHFFFAOYSA-N
Application
Reagent for the formylation of alcohols and amines. Hydroxylamines provide high yields of the N-formylated product.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
45.0 °F - closed cup
Flash Point(C)
7.2 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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David R Hill et al.
Organic letters, 4(1), 111-113 (2002-01-05)
[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.
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