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Merck

510475

Sigma-Aldrich

Bis(methylcyclopentadienyl)nickel(II)

97%

Synonym(s):

1,1′-Dimethylnickelocene

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About This Item

Linear Formula:
Ni(C5H4CH3)2
CAS Number:
Molecular Weight:
216.93
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

Assay

97%

form

liquid

reaction suitability

core: nickel
reagent type: catalyst

bp

85-90 °C/1 mmHg (lit.)

mp

34-36 °C (lit.)

storage temp.

2-8°C

SMILES string

[Ni].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2

InChI

1S/2C6H7.Ni/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;

InChI key

IHRNDXJDUYVDRB-UHFFFAOYSA-N

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1 of 4

This Item
700754SML3593T4069
(R)-SDP

700754

(R)-SDP

JC-1 powder or solid (Crystals)

T4069

JC-1

reaction suitability

core: nickel, reagent type: catalyst

reaction suitability

-

reaction suitability

-

reaction suitability

-

form

liquid

form

solid

form

powder

form

solid

storage temp.

2-8°C

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

room temp

bp

85-90 °C/1 mmHg (lit.)

bp

-

bp

-

bp

-

mp

34-36 °C (lit.)

mp

198-203 °C

mp

-

mp

-

Application

Reactant for synthesis of:
  • Nickel sandwich complexes
  • N-heterocyclic carbene complexes
  • Functionally substituted monocyclopentadienyl compounds

Features and Benefits

Volatile OMCVD precursor for the controlled growth of nickel nanoparticles on silicon substrates. Possible uses for metallic nickel nanoparticles embedded on silicon include the manufacture of high-density storage media 9. Nickel oxide thin films are generated via OMCVD in the presence of O2 or H2O2.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

150.8 °F - closed cup

Flash Point(C)

66 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Articles

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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